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Published in 2018 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2018.08.010
Abstract: Abstract Soot formation characteristics of ethene, propene, and 1-butene, the most abundant unsaturated intermediates in thermal decomposition of paraffinic hydrocarbons, were investigated in laminar diffusion flames stabilized on a co-flow burner installed in a high-pressure…
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Keywords:
diffusion flames;
butene;
soot;
propene butene ... See more keywords
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Published in 2020 at "Combustion and Flame"
DOI: 10.1016/j.combustflame.2020.08.051
Abstract: Abstract 1-butene is an important intermediate in combustion of various hydrocarbon fuels and oxygenated biofuels (e.g., butanol). Understanding its oxidation chemistry can help improve ignition and combustion process in advanced engines and provide better emission…
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Keywords:
stirred reactors;
low temperature;
temperature;
oxidation ... See more keywords
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Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.08.014
Abstract: Abstract The oligomerization of a mixed butene stream in liquid phase over amorphous aluminosilicates was investigated. The reaction products were analyzed with gas chromatography with special attention to the octene isomers. By varying temperature, content…
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Keywords:
amorphous aluminosilicates;
stream;
oligomerization mixed;
butene ... See more keywords
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Published in 2020 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2020.111218
Abstract: Abstract γ-Valerolactone (GVL) as a sustainable platform compound could be converted to renewable fuels and chemicals, whereas directly converting GVL to target products remains still the challenge. In this work, we report an amorphous SiO2-Al2O3…
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Keywords:
sio2 al2o3;
butene;
amorphous sio2;
ring opening ... See more keywords
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Published in 2021 at "Polymer"
DOI: 10.1016/j.polymer.2021.123408
Abstract: Abstract The mechanical properties and elastic behavior of Ziegler-Natta isotactic 1-butene-ethylene (BuEt-ZN) copolymers, having a broad composition from 1.7 to 45.5 mol% of ethylene units, are studied. The multi-site nature of the catalytic system determines a…
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Keywords:
ziegler natta;
mechanical properties;
ethylene;
butene ... See more keywords
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Published in 2021 at "Journal of Fuel Chemistry and Technology"
DOI: 10.1016/s1872-5813(21)60126-3
Abstract: Abstract The isomerization and hydroformylation of butene under the catalysis of Rh-BIPHEPHOS were investigated by varying the butene feed and reaction temperature. The results indicate that in the presence of syngas, with 1-butene as feed,…
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Keywords:
isomerization;
catalysis biphephos;
butene;
hydroformylation ... See more keywords
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Published in 2023 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c05683
Abstract: The environmental fate and transformation mechanism(s) of 1,3-butadiene (BD) under anoxic conditions remain largely unexplored. Anaerobic consortia that can biohydrogenate BD to stoichiometric amounts of 1-butene at a maximum rate of 205.7 ± 38.6 μM…
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Keywords:
butene;
biohydrogenation;
butadiene butene;
biohydrogenation butadiene ... See more keywords
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Published in 2019 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.8b06964
Abstract: Complete H–D exchange of butene was reported on a D-absorbed Pd–Au alloy surface. However, its reaction mechanism has not been clarified yet. Here we investigate the reaction of cis-2- and 1-butene on Pd70Au30(110) by means…
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Keywords:
absorbed alloy;
alloy surface;
mechanism;
butene ... See more keywords
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Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b20092
Abstract: The separation of mixed C4-olefins is a highly energy-intensive operation in the chemical industry due to the close boiling points of the unsaturated C4 isomers. In particular, the separation of trans/cis-2-butene is among the most…
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Keywords:
gallate based;
butene;
trans cis;
separation ... See more keywords
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Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12192
Abstract: Grafting metal cations to missing linker defect sites in zirconium-based metal-organic frameworks, such as UiO-66, produces a uniquely well-defined and homotopic catalytically active site. We present here the synthesis and characterization of a group of…
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Keywords:
butene;
butene adsorption;
activity;
dimerization ... See more keywords
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Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b09942
Abstract: Most C4 hydrocarbons are obtained as byproducts of ethylene production or oil refining, and complex and energy-intensive separation schemes are required for their isolation. Substantial industrial and academic effort has been expended to develop more…
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Keywords:
butene metal;
metal organic;
butene butene;
butene ... See more keywords