Emissive mononuclear Cu(I) triphenylphosphine complexes with functionalized 6-tert-butoxycarbonyl-2,2′-bipyridine
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DOI: 10.1007/s40242-018-7201-7
Abstract: Two new emissive mononuclear copper(I) triphenylphosphine complexes with functionalized 6-tert-butoxycarbonyl-2,2′-bipyridine chelating ligands were prepared and characterized. Each Cu(I) cation has a markedly distorted P2N2 tetrahedral array with two different Cu—N bond distances, due to the… read more here.
Keywords: tert butoxycarbonyl; bipyridine; emissive mononuclear; complexes functionalized ... See more keywords
Optical resolution of N-(t-butoxycarbonyl)leucine through mixed ligand complex formation with (R)-N-(2-pyridylmethyl)pipecolatocopper(II)
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DOI: 10.1016/j.ica.2017.06.052
Abstract: Abstract A copper(II) complex of (R)-N-(2-pyridylmethyl)pipecolate (pmpi) was prepared, and its structure was revealed by X-ray crystal structure analysis. Mixed ligand complexes were then prepared from this complex and (R)- and (S)-N-(t-butoxycarbonyl)leucinate (BocLeu). The (R)-BocLeu… read more here.
Keywords: bocleu complex; butoxycarbonyl; pyridylmethyl; mixed ligand ... See more keywords