Exploring the Influence of Diamagnetic Ions on the Mechanism of Magnetization Relaxation in {CoIII2LnIII2} (Ln = Dy, Tb, Ho) "Butterfly" Complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02720
Abstract: The synthesis and magnetic and theoretical studies of three isostructural heterometallic [CoIII2LnIII2(μ3-OH)2(o-tol)4(mdea)2(NO3)2] (Ln = Dy (1), Tb (2), Ho (3)) "butterfly" complexes are reported (o-tol = o-toluate, (mdea)2- = doubly deprotonated N-methyldiethanolamine). The CoIII ions… read more here.
Keywords: butterfly complexes; diamagnetic ions; ion; magnetization ... See more keywords
Reactivity of P4 butterfly complexes towards NHCs - generation of a metal-bridged P2 dumbbell complex.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc00615k
Abstract: The reactivity of the P4 butterfly complexes [{Cp'''Fe(CO)2}2(μ,η1:1-P4)] (A, Cp''' = C5H2tBu3) and [{Cp*Cr(CO)3}2(μ,η1:1-P4)] (B, Cp* = C5(CH3)5) towards the N-heterocyclic carbene IMe (1,3,4,5-tetramethyl-imidazol-2-ylidene) is reported. The reaction of A affords [P(IMe)2][Fe(CO)2Cp'''] (1) or [P(IMe)2][{Cp'''Fe}2(μ,η3:3-P3)]… read more here.
Keywords: bridged dumbbell; metal bridged; butterfly complexes; reactivity butterfly ... See more keywords