Articles with "butyl hydroperoxide" as a keyword



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Copper(ii) compounds with cetyltrimethylammonium bromide as an efficient catalytic system for tert-butyl hydroperoxide decomposition

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Published in 2020 at "Russian Chemical Bulletin"

DOI: 10.1007/s11172-020-2721-y

Abstract: Chelate compounds of copper(ii) demonstrated high catalytic activity in tert-butyl hydroperoxide decomposition in the presence of cetyltrimethylammonium bromide (CTAB). The feature of this catalytic system is that it ensures high reaction rate without visible sign… read more here.

Keywords: cetyltrimethylammonium bromide; system; hydroperoxide decomposition; tert butyl ... See more keywords
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Effect of the Phase Composition of Molybdenum Boride on its Catalytic Properties in the Epoxidation of 1-Octene by tert-Butyl Hydroperoxide

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Published in 2019 at "Theoretical and Experimental Chemistry"

DOI: 10.1007/s11237-019-09588-4

Abstract: It was shown that the epoxidation of 1-octene by tert-butyl hydroperoxide in the presence of Mo2B is accompanied by the formation of an amorphous oxygen-containing phase on its surface. It was established that this is… read more here.

Keywords: phase; epoxidation octene; octene tert; tert butyl ... See more keywords
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Tert-Butyl Hydroperoxide Stimulated Apoptosis Independent of Prostaglandin E2 and IL-6 in the HTR-8/SVneo Human Placental Cell Line

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Published in 2020 at "Reproductive Sciences"

DOI: 10.1007/s43032-020-00231-5

Abstract: Significant gaps exist in our knowledge of how cellular redox status, sometimes referred to as oxidative stress, impacts placental trophoblasts. The present study used tert-butyl hydroperoxide (TBHP) as a known generator of reactive oxygen species… read more here.

Keywords: tbhp; apoptosis; tert butyl; butyl hydroperoxide ... See more keywords
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Synthesis of N-Sulfonylformamidines by tert-butyl Hydroperoxide–Promoted, metal-free, direct oxidative dehydrogenation of aliphatic amines

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Published in 2018 at "Tetrahedron"

DOI: 10.1016/j.tet.2018.03.074

Abstract: Abstract A direct and convenient metal-free method to prepare sulfonyl amidines in the presence of aqueous tert-butyl hydroperoxide (T-HYDRO) has been developed. Different tertiary and secondary amines were tested for compatibility with the oxidative conditions… read more here.

Keywords: synthesis sulfonylformamidines; tert butyl; butyl hydroperoxide; sulfonylformamidines tert ... See more keywords
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Zn(II)-catalysed enantioselective addition of alcohols and tert-butyl hydroperoxide to isatin-derived N-Boc ketimines.

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Published in 2023 at "Chemical communications"

DOI: 10.1039/d3cc01527k

Abstract: Using binaphthyl-proline-based chiral ligands, Zn(II)-catalysed addition of alcohols and tert-butyl hydroperoxide to isatin-derived N-Boc ketimines provided the isatin-derived C3 N,O-aminals in up to 99% yield and up to 99% ee. The reactions could be carried… read more here.

Keywords: butyl hydroperoxide; isatin; alcohols tert; addition alcohols ... See more keywords
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NH4I/tert-Butyl Hydroperoxide-Promoted Oxidative C–N Cleavage of Tertiary Amines Leading to Nitroaromatic Compounds

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Published in 2017 at "Journal of Chemical Research"

DOI: 10.3184/174751917x15022797727991

Abstract: A NH4I/tert-butyl hydroperoxide-promoted oxidation of tertiary N-aryl-N,N-dialkylamines in DMSO has been developed to access nitroaromatic compounds. This methodology involves sequential N-dealkylation reactions in one-pot and a radical pathway is proposed. read more here.

Keywords: hydroperoxide promoted; nh4i tert; nitroaromatic compounds; tert butyl ... See more keywords
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Schisandrin B protects human keratinocyte-derived HaCaT cells from tert-butyl hydroperoxide-induced oxidative damage through activating the Nrf2 signaling pathway.

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Published in 2018 at "International journal of molecular medicine"

DOI: 10.3892/ijmm.2018.3901

Abstract: Schisandrin B (Sch B), an active extract of Schisandra chinensis, has demonstrated antioxidant activity in a number of in vitro and in vivo models. In the present study, the capacity of Sch B to protect against oxidative injury… read more here.

Keywords: keratinocyte derived; derived hacat; tert butyl; butyl hydroperoxide ... See more keywords