A new and convenient approach for the synthesis of P-stereogenic intermediates bearing a tert-butyl(methyl)phosphino group
Sign Up to like & getrecommendations! Published in 2017 at "Research on Chemical Intermediates"
DOI: 10.1007/s11164-017-2923-6
Abstract: Chiral organophosphorus compounds possessing a P-stereogenic center have been widely used as agricultural chemicals, pharmaceuticals, organocatalysts, and ligands for transition-metal catalysis. P-Stereogenic intermediates bearing a tert-butyl(methyl)phosphino group are important for the preparation of several commonly… read more here.
Keywords: phosphino group; tert butyl; stereogenic intermediates; methyl phosphino ... See more keywords
A highly stable and luminescent mononuclear Cu(I) bis-{5-tert-butyl-3-(6-methyl-2-pyridyl)-1H-1,2,4-triazole} complex
Sign Up to like & getrecommendations! Published in 2017 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2016.12.015
Abstract: Abstract A new emissive mononuclear homoleptic Cu(I) complex of 5-tert-butyl-3-(6-methyl-2-pyridyl)-1H-1,2,4-triazole (bmptzH), [Cu(bmptzH)2](ClO4) (1), has been synthesized by treatment of [Cu(PPh3)2(CH3CN)2](ClO4) or [Cu(CH3CN)4](ClO4) with the bmptzH ligand. It is revealed that complex 1 displays a distorted… read more here.
Keywords: methyl; pyridyl triazole; methyl pyridyl; tert butyl ... See more keywords
Effect of Oil on Cellulose Dissolution in the Ionic Liquid 1-Butyl-3-methyl Imidazolium Acetate
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DOI: 10.1021/acsomega.2c04311
Abstract: While ionic liquids (ILs) are well known to be excellent solvents for cellulose, the exact mechanism of dissolution has been a much disputed topic in recent years and is still not completely clear. In this… read more here.
Keywords: cellulose dissolution; effect; dissolution; oil ... See more keywords
Butyl-Methyl-Pyridinium Tetrafluoroborate Confined in Mesoporous Silica Xerogels: Thermal Behaviour and Matrix-Template Interaction
Sign Up to like & getrecommendations! Published in 2021 at "Materials"
DOI: 10.3390/ma14174918
Abstract: Organic-inorganic silica composites have been prepared via acid catalyzed sol-gel route using tetramethoxysilan (TMOS) and methyl-trimethoxysilane (MTMS) as silica precursors and n-butyl-3-methylpyridinium tetrafluoroborate ([bmPy][BF4]) as co-solvent and pore template, by varying the content of the… read more here.
Keywords: methyl pyridinium; tetrafluoroborate; pyridinium tetrafluoroborate; template ... See more keywords