Towards increased sustainability for aromatic polyesters: Poly(butylene 2,5-furandicarboxylate) and its blends with poly(butylene terephthalate)
Sign Up to like & getrecommendations! Published in 2020 at "Polymer"
DOI: 10.1016/j.polymer.2020.123157
Abstract: Abstract Eco-friendly engineering polyesters originating from monomers derived from biomass such as 2,5-furandicarboxylic acid (2,5-FDCA), constitute a family of materials that have recently attracted immense interest from industry and academia. Herein, poly(butylene 2,5-furandicarboxylate) (PBF) was… read more here.
Keywords: butylene furandicarboxylate; poly butylene; increased sustainability; butylene terephthalate ... See more keywords
Supramolecular structure, relaxation behavior and free volume of bio-based poly(butylene 2,5-furandicarboxylate)-block-poly(caprolactone) copolyesters.
Sign Up to like & getrecommendations! Published in 2023 at "Soft matter"
DOI: 10.1039/d2sm01359b
Abstract: In the present study, a fully plant-based sustainable copolyester series, namely poly(butylene 2,5-furandicarboxylate)-block-poly(caprolactone)s (PBF-block-PCL)s were successfully synthesized by melt polycondensation combining butylene 2,5-furandicarboxylate with polycaprolactone diol (PCL) at different weight ratios. Differential scanning calorimetry (DSC)… read more here.
Keywords: poly butylene; furandicarboxylate block; butylene furandicarboxylate; furandicarboxylate ... See more keywords
From PEF to PBF: What difference does the longer alkyl chain make a computational spectroscopy study of poly(butylene 2,5-furandicarboxylate)
Sign Up to like & getrecommendations! Published in 2022 at "Frontiers in Chemistry"
DOI: 10.3389/fchem.2022.1056286
Abstract: This work explores the conformational preferences and the structure-property correlations of poly(butylene 2,5-furandicarboxylate) (PBF), a longer chain analogue of the most well-known biobased polyester from the furan family, poly(ethylene 2,5-furandicarboxylate) (PEF). A thorough computational spectroscopic… read more here.
Keywords: pbf; structure; poly butylene; spectroscopy ... See more keywords
Partially renewable poly(butylene 2,5-furandicarboxylate-co-isophthalate) copolyesters obtained by ROP
Sign Up to like & getrecommendations! Published in 2018 at "Polymers"
DOI: 10.3390/books978-3-03897-452-9
Abstract: Cyclic butylene furandicarboxylate (c(BF)n) and butylene isophthalate (c(BI)n) oligomers obtained by high dilution condensation reaction were polymerized in bulk at 200 °C with Sn(Oct)2 catalyst via ring opening polymerization to give homopolyesters and copolyesters (coPBFxIy)… read more here.
Keywords: isophthalate units; butylene; partially renewable; butylene furandicarboxylate ... See more keywords
Co-Polymers based on Poly(1,4-butylene 2,5-furandicarboxylate) and Poly(propylene oxide) with Tuneable Thermal Properties: Synthesis and Characterization
Sign Up to like & getrecommendations! Published in 2019 at "Materials"
DOI: 10.3390/ma12020328
Abstract: Poly(ether ester)s (PEEs) represent a promising class of segmented co-polymers, nevertheless the synthesis of PEEs based on renewable 2,5-furandicarboxylic acid (FDCA) is still scarce. In this context, a series of poly(1,4-butylene 2,5-furandicarboxylate)-co-poly(poly(propylene oxide) 2,5-furandicarboxylate) co-polyesters… read more here.
Keywords: butylene furandicarboxylate; poly; poly butylene; propylene oxide ... See more keywords
Mechanical and Gas Barrier Properties of Poly(Lactic Acid) Modified by Blending with Poly(Butylene 2,5-Furandicarboxylate): Based on Molecular Dynamics
Sign Up to like & getrecommendations! Published in 2023 at "Polymers"
DOI: 10.3390/polym15071657
Abstract: Three blends of Poly(butylene 2,5-furandicarboxylate) (PBF) and Poly(lactic acid) (PLA) blends were modeled using molecular dynamics simulations, with PBF contents of 10%, 20%, and 30%, respectively. The study investigated the compatibilities of the blends, as… read more here.
Keywords: poly butylene; barrier properties; molecular dynamics; poly lactic ... See more keywords