Syntheses and crystal structures of new naphthalene- and anthracene-vanadate salts and an unprecedented dimetallabis(anthracene) sandwich complex: [Na(tetrahydrofuran)3][V2(anthracene)2].
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DOI: 10.1107/s2053229622001255
Abstract: Reduction of bis(naphthalene)vanadium(0) by potassium naphthalene (KNp) in tetrahydrofuran (THF) provides a highly reactive, thermolabile, and so far unisolable brown substance, which affords the first reported derivatives of bis(naphthalene)vanadates. From these solutions, thermally stable (298 K)… read more here.
Keywords: thf; vanadium; bis; c14h10 ... See more keywords