Synthesis and reactivity of propionitrilium derivatives of cobalt and iron bis(dicarbollides)
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DOI: 10.1039/d0nj03017a
Abstract: The synthesis of propionitrilium derivatives of cobalt and iron bis(dicarbollides) [8-EtCN-3,3′-M(1,2-C2B9H10)(1′,2′-C2B9H11)] (M = Co, Fe) by the reaction of the cesium salts of the parent bis(dicarbollide) anions [3,3′-M(1,2-C2B9H11)2]− with propionitrile in the presence of tert-butyl… read more here.
Keywords: derivatives cobalt; bis; c2b9h10 c2b9h11; cobalt iron ... See more keywords
Synthesis of Boronated Amidines by Addition of Amines to Nitrilium Derivative of Cobalt Bis(Dicarbollide)
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DOI: 10.3390/molecules26216544
Abstract: A series of novel cobalt bis(dicarbollide) based amidines were synthesized by the nucleophilic addition of primary and secondary amines to highly activated B-N+≡C–R triple bond of the propionitrilium derivative [8-EtC≡N-3,3′-Co(1,2-C2B9H10)(1′,2′-C2B9H11)]. The reactions with primary amines… read more here.
Keywords: cobalt bis; bis dicarbollide; c2b9h10 c2b9h11; addition ... See more keywords