Fine‐Tuned Ultra‐Microporous Metal–Organic Framework in Mixed‐Matrix Membrane: Pore‐Tailoring Optimization for C2H2/C2H4 Separation
Sign Up to like & getrecommendations! Published in 2022 at "Advanced Materials"
DOI: 10.1002/adma.202204553
Abstract: Effective separation of ethyne from ethyne/ethylene (C2H2/C2H4) mixtures is a challenging and crucial industrial process. Herein, an ultra‐microporous metal–organic framework (MOF) platform, Cd(dicarboxylate)2(ditriazole), with triangular channels is proposed for high‐efficiency separation of C2H2 from C2H4.… read more here.
Keywords: framework; c2h2; c2h2 c2h4; separation ... See more keywords
A New Cu(II)-Based Metal–Organic Framework for Highly Selective C2H2/C2H4 Separation and Prevention Against Carcinogenesis of Cirrhosis via Down-Regulating the CXCR3 Mediated Inflammatory Pathway
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Cluster Science"
DOI: 10.1007/s10876-019-01676-8
Abstract: In this study, by using a mixed-ligand approach, a novel Cu(II)-based metal–organic framework {[Cu(oba)(azd)0.5]·(DMF)2}n (1) with a three-dimensional framework has been successfully prepared by reaction of the V-shape linker 4,4′-oxydibenzoic acid (H2oba) with a azo-functionalized… read more here.
Keywords: c2h2 c2h4; framework; metal organic; based metal ... See more keywords
Fe-MOF with U-Shaped Channels for C2H2/CO2 and C2H2/C2H4 Separation.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03236
Abstract: The development of high-performance adsorbents is critical for the low-energy separation of acetylene. Herein, we synthesized an Fe-MOF (MOF, metal-organic framework) with U-shaped channels. The adsorption isotherms of C2H2, C2H4, and CO2 show that the… read more here.
Keywords: mof; shaped channels; c2h2 c2h4; separation ... See more keywords
Potential of a pH-Stable Microporous MOF for C2H2/C2H4 and C2H2/CO2 Gas Separations under Ambient Conditions.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03275
Abstract: Cost-effective adsorption-based C2H2/C2H4 and C2H2/CO2 gas separations are extremely important in the industry. Herein, a pH-stable three-dimensional (3D) metal-organic framework (MOF), IITKGP-25, possessing exposed functional sites is presented, which facilitates such separations with excellent ideal… read more here.
Keywords: gas; c2h2; c2h2 c2h4; c2h4 c2h2 ... See more keywords
Fine-Tuning MOFs with Amino Group for One-Step Ethylene Purification from the C2 Hydrocarbon Mixture.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c01056
Abstract: Due to the similar kinetic diameters of C2H2, C2H4, and C2H6, one-step purification of C2H4 from a ternary C2H2/C2H4/C2H6 mixture by adsorption separation is still a challenge. Based on a C2H6-trapping platform and crystal engineering… read more here.
Keywords: purification; c2h4; one step; mixture ... See more keywords
Three novel MOFs constructed from 1,3,5-tris(1-imidazolyl)benzene and dicarboxylate ligands with selective adsorption for C2H2/C2H4 and C2H6/CH4.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04149e
Abstract: The urothermal reactions of Co(II)/Zn(II) salts with the diverse carboxylic acid and 1,3,5,-tris(1-imidazolyl)benzene(tib) ligands afforded three novel MOFs, namely, [Co3(tib)2(abdc)2(ox)]2·6H2O (1), [Co3O(tib)(abdc)2(DMI)]·2DMI·2H2O (2) and [Zn3I2(tib)2(napdc)2]·2DMI·2H2O (3), (H2abdc = 5-amino-1,3-benzenedicarboxylate, H2napdc = 1,4-naphthalene dicarboxylic acid and… read more here.
Keywords: c2h4; imidazolyl benzene; novel mofs; c2h2 c2h4 ... See more keywords
A charge-decorated porous framework with polar pores and open O donor sites for CO2/CH4 and C2H2/C2H4 separations.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01961b
Abstract: Developing efficient adsorbent materials towards energy gas purification, e.g. CO2 removal from natural gas or hydrocarbon separation, is an important but extremely challenging task. Herein, taking advantage of a cationic bipyridinium ligand in competition with… read more here.
Keywords: donor sites; co2 ch4; c2h2 c2h4; open donor ... See more keywords
Pillar-layer Zn–triazolate–dicarboxylate frameworks with a customized pore structure for efficient ethylene purification from ethylene/ethane/acetylene ternary mixtures
Sign Up to like & getrecommendations! Published in 2023 at "Chemical Science"
DOI: 10.1039/d3sc01134h
Abstract: The selective adsorption of C2H6 and C2H2 over C2H4 from C2H2/C2H4/C2H6 ternary mixtures for one-step C2H4 purification represents a crucial yet challenging task in industry. The pore structure of the adsorbents must be finely tailored… read more here.
Keywords: c2h4; triazolate dicarboxylate; ternary mixtures; c2h2 c2h4 ... See more keywords