Acetylene-Triggered Gate-Opening Behavior in a Stable Rigid-Flexible MOF for Efficient C2H2/CO2 Separation.
Sign Up to like & getrecommendations! Published in 2025 at "Advanced materials"
DOI: 10.1002/adma.202514488
Abstract: High‐purity acetylene (C2H2) is indispensable in the chemical industry. However, C2H2 produced via the calcium carbide process contains trace CO2 impurities, necessitating purification. Due to their comparable molecular dimensions (3.3 × 3.3 × 5.7 Å3… read more here.
Keywords: efficient c2h2; separation; co2; mof ... See more keywords
Highly selective C2H2 and CO2 capture and photoluminescence properties of two Tb(III)-based MOFs
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2020.121257
Abstract: Abstract Two new complexes, namely, [Tb0.5L(HCOO)0.5]n (1), {[Tb2(L)4(H2O)]·2NO3}n (2) were solvothermally constructed based on N-heterocyclic dicarboxylate ligand (H2L, 4-(1-(4-carboxylatobenzyl)pyridinium-4-yl)benzoic). Complex 1 is a 3D porous framework. 2 is a 3D supramolecular architecture constructed from 1D… read more here.
Keywords: co2 capture; highly selective; capture photoluminescence; c2h2 co2 ... See more keywords
A pacs-type metal-organic framework based on [Cd3(OH)] clusters for effective C2H2/CO2 separation and fluorescent detection of TNP in water
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2020.121658
Abstract: Abstract Metal-organic frameworks (MOFs) have become a versatile platform for gas capture/separation and luminescent sensing of toxic pollutants, and the combination of both of these properties depends on the robust framework and pre-designed pore functionality… read more here.
Keywords: cd3; framework; metal organic; c2h2 co2 ... See more keywords
Finely Tuned Framework Isomers for Highly Efficient C2H2 and CO2 Separation.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00507
Abstract: Obtaining the optimal physiadsorbents based on the same starting materials is one of the crucial technologies that can address the increasing problem of energy-consuming separation. Herein, a group of porous coordination isomers (NTU-51 to NTU-54)… read more here.
Keywords: co2 separation; c2h2 co2; c2h2; finely tuned ... See more keywords
Uncoordinated Hexafluorosilicates in a Microporous Metal-Organic Framework Enabled C2H2/CO2 Separation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00409
Abstract: Metal-organic frameworks (MOFs) represent a kind of low-energy physisorbent with modifiable pores and framework structures; however, a deep understanding of how these structural features influence properties is a prerequisite for the rational design and development… read more here.
Keywords: separation; c2h2 co2; uncoordinated hexafluorosilicates; metal organic ... See more keywords
Fe-MOF with U-Shaped Channels for C2H2/CO2 and C2H2/C2H4 Separation.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03236
Abstract: The development of high-performance adsorbents is critical for the low-energy separation of acetylene. Herein, we synthesized an Fe-MOF (MOF, metal-organic framework) with U-shaped channels. The adsorption isotherms of C2H2, C2H4, and CO2 show that the… read more here.
Keywords: mof; shaped channels; c2h2 c2h4; separation ... See more keywords
Potential of a pH-Stable Microporous MOF for C2H2/C2H4 and C2H2/CO2 Gas Separations under Ambient Conditions.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03275
Abstract: Cost-effective adsorption-based C2H2/C2H4 and C2H2/CO2 gas separations are extremely important in the industry. Herein, a pH-stable three-dimensional (3D) metal-organic framework (MOF), IITKGP-25, possessing exposed functional sites is presented, which facilitates such separations with excellent ideal… read more here.
Keywords: gas; c2h2; c2h2 c2h4; c2h4 c2h2 ... See more keywords
Boosting the C2H2/CO2 Separation Performance of Metal-Organic Frameworks through Fluorine Substitution.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00954
Abstract: A pair of metal-organic frameworks (MOFs) of JXNU-15 (formulated as [Co6(μ3-OH)6(BTB)2(BPY)3]n, BTB3- = benzene-1,3,5-tribenzoate and BPY = 4,4'-bipyridine) and its fluorinated JXNU-15(F) ([Co6(μ3-OH)6(SFBTB)2(BPY)3]n) based on the fluorous 1,3,5-tri(3,5-bifluoro-4-carboxyphenyl)benzene (SFBTB3-) ligands were presented. The detailed comparisons… read more here.
Keywords: jxnu; c2h2 co2; co2 separation; separation performance ... See more keywords
Microporous Na-Nd Heterometallic Organic Frameworks for C2H2/CO2 and C3H4/C3H6 Separation.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c01077
Abstract: Selective adsorption of alkynes using porous materials is an energy- and cost-saving potential separation technique compared to low-temperature distillation. However, developing suitable adsorbents remains a significant challenge due to the high similarity between alkynes and… read more here.
Keywords: separation; co2 c3h4; c2h2 co2; c3h4 c3h6 ... See more keywords
C2H2/CO2 Separation by a Carborane Hybrid 2D Metal-Organic Framework.
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DOI: 10.1021/acs.inorgchem.5c01518
Abstract: The separation of acetylene (C2H2) from carbon dioxide (CO2) is important in industry but challenging due to their similar physical properties. Herein, a boron-rich 2D metal-organic framework ZNU-14 based on the carborane backbone was readily… read more here.
Keywords: separation; c2h2; c2h2 co2; co2 separation ... See more keywords
Ni8 Carboxylate Metal-Organic Frameworks.
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DOI: 10.1021/acs.inorgchem.5c02922
Abstract: Octanuclear nickel cube (Ni8) is considered as a highly attractive inorganic building block in the field of metal-organic frameworks (MOFs) due to its high symmetry (Oh), 12 connection sites, and excellent chemical stability of the… read more here.
Keywords: organic frameworks; carboxylate metal; c2h2 co2; ni8 carboxylate ... See more keywords