Highly selective C2H2 and CO2 capture and photoluminescence properties of two Tb(III)-based MOFs
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2020.121257
Abstract: Abstract Two new complexes, namely, [Tb0.5L(HCOO)0.5]n (1), {[Tb2(L)4(H2O)]·2NO3}n (2) were solvothermally constructed based on N-heterocyclic dicarboxylate ligand (H2L, 4-(1-(4-carboxylatobenzyl)pyridinium-4-yl)benzoic). Complex 1 is a 3D porous framework. 2 is a 3D supramolecular architecture constructed from 1D… read more here.
Keywords: co2 capture; highly selective; capture photoluminescence; c2h2 co2 ... See more keywords
A pacs-type metal-organic framework based on [Cd3(OH)] clusters for effective C2H2/CO2 separation and fluorescent detection of TNP in water
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2020.121658
Abstract: Abstract Metal-organic frameworks (MOFs) have become a versatile platform for gas capture/separation and luminescent sensing of toxic pollutants, and the combination of both of these properties depends on the robust framework and pre-designed pore functionality… read more here.
Keywords: cd3; framework; metal organic; c2h2 co2 ... See more keywords
Finely Tuned Framework Isomers for Highly Efficient C2H2 and CO2 Separation.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00507
Abstract: Obtaining the optimal physiadsorbents based on the same starting materials is one of the crucial technologies that can address the increasing problem of energy-consuming separation. Herein, a group of porous coordination isomers (NTU-51 to NTU-54)… read more here.
Keywords: co2 separation; c2h2 co2; c2h2; finely tuned ... See more keywords
Uncoordinated Hexafluorosilicates in a Microporous Metal-Organic Framework Enabled C2H2/CO2 Separation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00409
Abstract: Metal-organic frameworks (MOFs) represent a kind of low-energy physisorbent with modifiable pores and framework structures; however, a deep understanding of how these structural features influence properties is a prerequisite for the rational design and development… read more here.
Keywords: separation; c2h2 co2; uncoordinated hexafluorosilicates; metal organic ... See more keywords
Fe-MOF with U-Shaped Channels for C2H2/CO2 and C2H2/C2H4 Separation.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03236
Abstract: The development of high-performance adsorbents is critical for the low-energy separation of acetylene. Herein, we synthesized an Fe-MOF (MOF, metal-organic framework) with U-shaped channels. The adsorption isotherms of C2H2, C2H4, and CO2 show that the… read more here.
Keywords: mof; shaped channels; c2h2 c2h4; separation ... See more keywords
Potential of a pH-Stable Microporous MOF for C2H2/C2H4 and C2H2/CO2 Gas Separations under Ambient Conditions.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03275
Abstract: Cost-effective adsorption-based C2H2/C2H4 and C2H2/CO2 gas separations are extremely important in the industry. Herein, a pH-stable three-dimensional (3D) metal-organic framework (MOF), IITKGP-25, possessing exposed functional sites is presented, which facilitates such separations with excellent ideal… read more here.
Keywords: gas; c2h2; c2h2 c2h4; c2h4 c2h2 ... See more keywords
Boosting the C2H2/CO2 Separation Performance of Metal-Organic Frameworks through Fluorine Substitution.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00954
Abstract: A pair of metal-organic frameworks (MOFs) of JXNU-15 (formulated as [Co6(μ3-OH)6(BTB)2(BPY)3]n, BTB3- = benzene-1,3,5-tribenzoate and BPY = 4,4'-bipyridine) and its fluorinated JXNU-15(F) ([Co6(μ3-OH)6(SFBTB)2(BPY)3]n) based on the fluorous 1,3,5-tri(3,5-bifluoro-4-carboxyphenyl)benzene (SFBTB3-) ligands were presented. The detailed comparisons… read more here.
Keywords: jxnu; c2h2 co2; co2 separation; separation performance ... See more keywords
Solvatomorphism Influence of Porous Organic Cage on C2H2/CO2 Separation.
Sign Up to like & getrecommendations! Published in 2021 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c04573
Abstract: Porous organic molecular (POM) materials can exhibit solvatomorphs via altering their crystallographic packing in the solid state, but investigating real gas mixture separation by porous materials with such a behavior is still very rare. Herein,… read more here.
Keywords: organic cage; cpoc 101; porous organic; c2h2 co2 ... See more keywords
Rational Pore Design of a Cage-like Metal-Organic Framework for Efficient C2H2/CO2 Separation.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c17196
Abstract: Considering the importance of C2H2 in industry, it is of great significance to develop porous materials for efficient C2H2/CO2 separation. Besides the high selectivity, the C2H2 adsorption capacity is another vital factor in C2H2/CO2 separation.… read more here.
Keywords: c2h2; pore; c2h2 co2; co2 separation ... See more keywords
Efficient C2H2/CO2 Separation in Ultramicroporous Metal-Organic Frameworks with Record C2H2 Storage Density.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c07191
Abstract: Physical separation of C2H2 from CO2 on metal-organic frameworks (MOFs) has received substantial research interest due to the advantages of simplicity, security, and energy efficiency. However, that C2H2 and CO2 exhibit very close physical properties… read more here.
Keywords: c2h2; mof; metal; c2h2 co2 ... See more keywords
Vertex Strategy in Layered 2D MOFs: Simultaneous Improvement of Thermodynamics and Kinetics for Record C2H2/CO2 Separation Performance.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c01784
Abstract: Developing adsorbents with multiple merits in capacity, selectivity, mass transfer, and stability toward C2H2/CO2 separation is crucial and challenging for producing high-purity C2H2 for advanced polymers and the electronic industry. Here, we demonstrate a vertex… read more here.
Keywords: thermodynamics; co2 separation; c2h2; vertex strategy ... See more keywords