Solid-state transformations by thermal decomposition of [Co(en)3][Fe(C2O4)3] in an inert atmosphere
Sign Up to like & getrecommendations! Published in 2020 at "Thermochimica Acta"
DOI: 10.1016/j.tca.2020.178578
Abstract: Abstract The thermal decomposition was investigated for the double complex compound (DCC) [Co(en)3][Fe(C2O4)3] in an argon atmosphere at a heating rate of 5 K/min and the initial amount of complex 20−30 mmol. The composition of solid decomposition… read more here.
Keywords: solid state; transformations thermal; state transformations; c2o4 ... See more keywords
Direct Observation of C2O4•- and CO2•- by Oxidation of Oxalate within Nanogap of Scanning Electrochemical Microscope.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b08900
Abstract: Oxalate oxidation in the presence of different oxidized luminophores leads to the emission of light and has been studied extensively in electrogenerated chemiluminescence (ECL). The proposed mechanism involves the initial formation of the oxalate radical… read more here.
Keywords: oxidation; scanning electrochemical; co2; c2o4 ... See more keywords
Ladder-like [CrCu] coordination polymers containing unique bridging modes of [Cr(C2O4)3]3- and Cr2O72.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01195a
Abstract: Three heterometallic one-dimensional (1D) coordination polymers {A[CrCu2(bpy)2(C2O4)4]·H2O}n [A = K+ (1) and NH4+ (2); bpy = 2,2'-bipyridine] and [(Cr2O7)Cu2(C2O4)(phen)2]n (3; phen = 1,10-phenanthroline) with uncommon topology have been synthesized using a building block approach and… read more here.
Keywords: ladder like; like crcu; bridging modes; coordination polymers ... See more keywords
Oxalate-based [CuIICrIII] coordination compounds affected by the tridentate ligand, simple anion, and reactant ratio: structural and magnetic features.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01949c
Abstract: Seven novel oxalate-based [CuIICrIII] compounds: [Cu4(terpy)4Cl5][Cr(C2O4)3]·9H2O (1; terpy = 2,2':6',2''-terpyridine), {[Cr2Cu4(H2O)2(terpy)4(C2O4)7]·10H2O}n (2), [Cr2Cu4(H2O)2(terpy)4(C2O4)7]·12H2O (3), [Cu(H2O)3(terpy)][CrCu(H2O)(terpy)(C2O4)3]2·9H2O (4), [Cu(H2O)(terpy)(NO3)][CrCu(H2O)(terpy)(C2O4)3]·6H2O (5), [CrCu2(terpy)2(C2O4)3(NO3)]·1.5H2O·CH3OH (6) and [Cr2Cu4(H2O)4(terpy)4(C2O4)6][Cr2Cu2(terpy)2(C2O4)6]·9H2O·CH3OH (7) were obtained from the reaction of an aqueous solution of the building… read more here.
Keywords: h2o terpy; ligand; terpy; c2o4 ... See more keywords
Effect of adding K3[Fe(C2O4)3] on the characteristics of the magnesium alloy micro-arc oxidation coating
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Dispersion Science and Technology"
DOI: 10.1080/01932691.2019.1617735
Abstract: Abstract The black micro-arc oxidation (MAO) thermal control coating was prepared in the electrolyte containing Na3PO4, K3[Fe(C2O4)3], C6H11KO7 and NaOH. The complexion mechanism of iron(III) complexes was studied. The effect of adding K3[Fe(C2O4)3] on electrolyte… read more here.
Keywords: micro arc; adding c2o4; effect adding; mao coating ... See more keywords
Syntheses and crystal structures of three novel oxalate coordination compounds: Rb2Co(C2O4)2·4H2O, Rb2CoCl2(C2O4) and K2Li2Cu(C2O4)3·2H2O
Sign Up to like & getrecommendations! Published in 2023 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989023001822
Abstract: Rb2Co(C2O4)2·4H2O consists of isolated [Co(C2O4)2·2H2O] octahedra which are connected only by hydrogen bonding of the water molecules. Rb2CoCl2(C2O4) consists of chains of Co2+ cations connected via oxalate bridging ligands. In K2Li2Cu(C2O4)3·2H2O, the metal cations are… read more here.
Keywords: rb2co c2o4; rb2cocl2 c2o4; k2li2cu c2o4; c2o4 4h2o ... See more keywords