Aromaticity-Driven Molecular Structural Variation and Electronic Configuration Alternation: An Example of Cyclic π Conjugation Involving a Mo-Mo δ Bond.
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DOI: 10.1021/acs.inorgchem.7b02133
Abstract: We have synthesized and characterized the mixed-ligand dimolybdenum paddlewheel complex Na[(DAniF)3Mo2(C3S5)] (Na[1]; DAniF = N,N'-di-p-anisylformamidinate, dmit = 1,3-dithiole-2-thione-4,5-dithiolate), which has a six-membered chelating [Mo2S2C2] ring created by equatorial coordination of the dmit (C3S5) ligand to… read more here.
Keywords: aromaticity; c3s5; bond; core ... See more keywords