LAUSR

Intramolecular Interactions between the Pnictogen Groups in a Rigid Ferrocene Phosphinostibine and the Corresponding Phosphine Chalcogenides, Stiboranes, and Their Complexes

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0 Published in 2025 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.5c01332

Abstract: Differences in the chemical properties of phosphorus and antimony enable the synthesis of heteroditopic derivatives whose properties can be modified by altering the pnictogen substituents. In this work, 1-(diphenylstibino)-2-(dicyclohexylphosphino)ferrocene, [Fe(η5-1-Ph2Sb-2-Cy2PC5H3)(η5-C5H5)] (1), and the corresponding phosphine… read more here.

Keywords: intramolecular interactions; c5h5; corresponding phosphine; phosphine chalcogenides ... See more keywords

Mystery of 1-Vinylpropargyl Formation from Acetylene Addition to the Propargyl Radical: An Open-and-Shut Case.

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0 Published in 2017 at "Journal of Physical Chemistry A"

DOI: 10.1021/acs.jpca.6b12996

Abstract: The addition of acetylene (C2H2) to the propargyl radical (C3H3) initiates a cascade of molecular weight growth reactions that result in the production of polycyclic aromatic hydrocarbons (PAHs) in flames. Although it is well-established that… read more here.

Keywords: c5h5; addition; open shut; formation ... See more keywords

Syntheses, rearrangements, and structural analyses of unsaturated nitrogen donor ligands derived from diphenyldiazomethane and the chiral rhenium Lewis acid [(η5-C5H5)Re(NO)(PPh3)].

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1 Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt00890d

Abstract: Diphenyldiazomethane and a labile chlorobenzene complex of [(η5-C5H5)Re(NO)(PPh3)]+ BF4- react to give the η1 adduct [(η5-C5H5)Re(NO)(PPh3)(NNCPh2)]+ BF4- (73%). When this is conducted in the presence of copper powder, a 3-phenyl-1H-indazole complex derived from carbon-hydrogen bond… read more here.

Keywords: c5h5; chch; rhenium; c5h5 pph3 ... See more keywords

σ-Arsolido complexes.

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0 Published in 2024 at "Dalton transactions"

DOI: 10.1039/d4dt01308e

Abstract: The σ-stannyl complexes [M(SnnBu3)(CO)n(η5-C5H5)] (n = 3, M = Mo, W; n = 2, M = Fe) serve as mild reagents for the installation of σ-arsolyl ligands in transmetallation reactions with As-chloro-arsoles ClAsC4R4 (R =… read more here.

Keywords: arsolido complexes; snnbu3 c5h5; c5h5; reaction snnbu3 ... See more keywords