Half-sandwich hydrazine complexes of iridium: Preparation and reactivity
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.04.016
Abstract: Abstract Chloro complexes IrCl2(η5-C5Me5)[P(OR)3] (1) (R Me, Et) were prepared by reacting dimer [IrCl2(η5-C5Me5)]2 with phosphites in alcohol. Treatment of 1 with R1NHNH2 gave monohydrazine complexes [IrCl(η5-C5Me5)(R1NHNH2){P(OR)3}]BPh4 (2, 3, 4) [R1 H (2), Me (3),… read more here.
Keywords: bph4; hydrazine complexes; c5me5 phn; c5me5 ... See more keywords
Synthesis and Reduction of Heteroleptic Bis(cyclopentadienyl) Uranium(III) Complexes.
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DOI: 10.1021/acs.inorgchem.2c00322
Abstract: Heteroleptic U(III) complexes supported by bis(cyclopentadienyl) frameworks have been synthesized to examine their suitability as precursors to U(II) complexes. The newly synthesized (C5Me5)2U(OC6H2tBu2-2,6-Me-4), (C5Me5)2U(OC6H2Ad2-2,6-tBu-4) (Ad = 1-adamantyl), (C5Me5)2U(C5H5), and (C5Me5)2U(C5Me4H) are compared with (C5Me5)2U[N(SiMe3)2], (C5Me5)2U[CH(SiMe3)2],… read more here.
Keywords: c5me5; bis cyclopentadienyl; c5me5 sime3; iii complexes ... See more keywords
Tris(pentamethylcyclopentadienyl) Complexes of Late Lanthanides Tb, Dy, Ho, and Er: Solution and Mechanochemical Syntheses and Structural Comparisons
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DOI: 10.1021/acs.organomet.7b00385
Abstract: The tris(pentamethylcyclopentadienyl) complexes, (C5Me5)3Ln (Ln = Tb, Dy, Ho, and Er), have been synthesized to determine if structural trends observed with the larger rare-earth metals, La–Gd, extend to the smaller metals and to determine the… read more here.
Keywords: tris pentamethylcyclopentadienyl; lanthanides solution; late lanthanides; c5me5 ... See more keywords
Identification of the U(V) complex (C5Me5)2UVI(NSiMe3) in the reaction of (C5Me5)2UIIII(THF) with N3SiMe3.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01926d
Abstract: The U(V) imido complex (C5Me5)2UVI(NSiMe3), 1, was crystallographically characterized from the reaction of (C5Me5)2UIIII(THF) with N3SiMe3 which demonstrates that it can be an intermediate in the reaction which ultimately forms (C5Me5)2UVI(NSiMe3)2 and (C5Me5)2UIVI2. U(V) intermediates… read more here.
Keywords: c5me5; reaction; reaction c5me5; 2uvi nsime3 ... See more keywords