Structural, Spectroscopic, and Computational Analysis of Heterometallic Thorium Phosphinidiide Complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02308
Abstract: To synthesize complexes with thorium-phosphorus multiple-bond character, reactions of (C5Me5)2Th[P(H)Mes]2 with monovalent alkali-metal bases, MN(SiMe3)2, as well as CuMes, have been investigated. The results with MN(SiMe3)2 are phosphinidiide complexes of the form {(C5Me5)2Th[μ2-P(Mes)][μ2-P(H)Mes]M(L)n}2 (M =… read more here.
Keywords: c5me5 2th; phosphinidiide complexes; thorium; structural spectroscopic ... See more keywords
Reactivity of a Lewis Base Supported Thorium Terminal Imido Metallocene toward Small Organic Molecules
Sign Up to like & getrecommendations! Published in 2017 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00212
Abstract: The Lewis base supported thorium terminal imido metallocene (η5-C5Me5)2Th═N(mesityl)(DMAP) (1) reacts with various small organic molecules such as thiazoles, silanes, internal acetylenes, nitriles, ketones, CS2, isothiocyanates, carbodiimides, lactides, organic azides, and diazoalkane derivatives. For example,… read more here.
Keywords: supported thorium; c5me5 2th; thorium terminal; base supported ... See more keywords