Synthesis and Reduction of Heteroleptic Bis(cyclopentadienyl) Uranium(III) Complexes.
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DOI: 10.1021/acs.inorgchem.2c00322
Abstract: Heteroleptic U(III) complexes supported by bis(cyclopentadienyl) frameworks have been synthesized to examine their suitability as precursors to U(II) complexes. The newly synthesized (C5Me5)2U(OC6H2tBu2-2,6-Me-4), (C5Me5)2U(OC6H2Ad2-2,6-tBu-4) (Ad = 1-adamantyl), (C5Me5)2U(C5H5), and (C5Me5)2U(C5Me4H) are compared with (C5Me5)2U[N(SiMe3)2], (C5Me5)2U[CH(SiMe3)2],… read more here.
Keywords: c5me5; bis cyclopentadienyl; c5me5 sime3; iii complexes ... See more keywords