Synthesis, Characterization, and Light Sensitivity in Titanium Piano Stool Alkyl and Sulfur Complexes, [(C5Me5)TiMe2R] n− (R = Me, SCPh3, S; n = 0, 1)
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DOI: 10.1021/acs.organomet.5c00080
Abstract: The piano stool complex (C5Me5)TiMe3, 1, reacts with HSCPh3 to produce (C5Me5)TiMe2(SCPh3), 2. Reduction of 2 with an alkali metal (K or Na) produces the sulfide complexes [K(crypt)][(C5Me5)TiMe2(S)], 3-K(crypt), and (C5Me5)TiMe2(μ-S)M(18-crown-6), 3-M(18c6) (M = K,… read more here.
Keywords: titanium; c5me5 time2; piano; synthesis characterization ... See more keywords