Ligand-Based Reactivity of Oxygenation and Alkylation in Cobalt Complexes Binding with (Thiolato)phosphine Derivatives.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b03740
Abstract: In our efforts to understand the nature of metal thiolates, we have explored the chemistry of cobalt ion supported by (thiolato)phosphine ligand derivatives. Herein, we synthesized and characterized a square-planar CoII complex binding with a… read more here.
Keywords: thiolato phosphine; ligand based; c6h3; phosphine ... See more keywords
Titanocene pnictinidene complexes.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01305j
Abstract: The phospha-Wittig reagent MesTerPPMe3 (MesTer = 2,6-{2,4,6-Me3-C6H2}-C6H3) and arsa-Wittig reagent DipTerAsPMe3 (DipTer = 2,6-{2,6-iPr2-C6H3}-C6H3) have been employed to synthesize the titanocene complexes Cp2Ti(PMe3)PnAr (Pn = P, As) with terminal phosphinidene or arsinidene ligands, respectively. Ab… read more here.
Keywords: titanocene pnictinidene; c6h3; pnictinidene complexes;