Pt(II) and Pd(II)-assisted coupling of nitriles and 1,3-diiminoisoindoline: Synthesis and luminescence properties of (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pt(II) and Pd(II) complexes
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.05.036
Abstract: Abstract Treatment of trans-[PtCl2(NCR)2] 1 (R = Me (1a), Et (1b), o-ClC6H4 (1c), p-ClC6H4 (1d), p-(HC O)C6H4 (1e), p-O2NC6H4CH2 (1f)) with 1,3-diiminoisoindoline HN CC6H4C(NH) NH 2 gives access to the corresponding (1,3,5,7,9-pentaazanona-1,3,6,8-tetraenato)Pt(II) complexes [PtCl{NH C(R)N C(C6H4)NC NC(R)… read more here.
Keywords: c6h4; tetraenato complexes; luminescence; pentaazanona tetraenato ... See more keywords
Platinum Assisted Tandem P-C Bond Cleavage and P-N Bond Formation in Amide Functionalized Bisphosphine o-Ph2PC6H4C(O)N(H)C6H4PPh2-o: Synthesis, Mechanistic, and Catalytic Studies.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02515
Abstract: The reactions of amide functionalized bisphosphine o-Ph2PC6H4C(O)N(H)C6H4PPh2-o (1) with platinum salts are described. Treatment of 1 with [Pt(COD)Cl2] yielded a chelate complex, [PtCl2{o-Ph2PC6H4C(O)N(H)C6H4PPh2-o}κ2-P,P] (2), which on subsequent treatment with LiHMDS formed a novel 1,2-azaphospholene-phosphine complex… read more here.
Keywords: formation; ph2pc6h4c c6h4pph2; c6h4; bond ... See more keywords
Nitro End Groups: Remarkable Vibrational Reporters for Charge Transfer in the Excited States of Oligo(p-phenyleneethynylene)-Bridged Donor–Acceptor Dyads
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DOI: 10.1021/acs.jpcc.0c01532
Abstract: The D-π-A dyads [(n-Hex)2N(1,4-C6H4)]C≡C[(1,4-C6H4)NO2] (1) and [(n-Hex)2N(1,4-C6H4)]C≡C(1,4-C6H4)C≡C[(1,4-C6H4)NO2] (2) have been studied by ultrafast time-resolved infrared absorption spectroscop... read more here.
Keywords: remarkable vibrational; c6h4; groups remarkable; c6h4 c6h4 ... See more keywords
Molybdenum Benzylidyne Complexes for Olefin Metathesis Reactions
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DOI: 10.1021/acs.organomet.0c00491
Abstract: The molybdenum benzylidynes [ArC≡Mo(OC(CF3)2CH3)3(1,2-dimethoxyethane)], where Ar = Ph (2a), p-(OCH3)C6H4 (2b), p-(CF3)C6H4 (2c), p-(NO2)C6H4 (2d), or 4-(NO2)-3-(CF3)C6H3 (2e), and [p-(NO2)C6H4C≡Mo... read more here.
Keywords: molybdenum benzylidyne; c6h4; benzylidyne complexes; olefin metathesis ... See more keywords
Modulation of an Anagostic Interaction in SiPSi-Type Pincer Platinum Complexes
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00269
Abstract: The reactivities of tris(benzyldimethylsilyl)phosphine [P(o-C6H4-CH2SiMe2H)3] (1) and tris(benzyldiphenylsilyl)phosphine [P(o-C6H4-CH2SiPh2H)3] (6) toward the same platinum precursor [Pt(PPh3)3] are strikingly different. The reaction with 1 renders the trans disilyl platinum(II) complex [Pt{P(o-C6H4-CH2SiMe2)2(o-C6H4-CHSiMe2)}PPh3] (2) in which the ligand… read more here.
Keywords: modulation anagostic; platinum; interaction sipsi; anagostic interaction ... See more keywords
Synthesis, structural characterization and in vitro antiproliferative effects of novel organotin(iv) compounds with nicotinate and isonicotinate moieties on carcinoma cells
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d0nj05069e
Abstract: In recent decades, organotin(IV) chemistry has seen a rapid growth owing to the biological, pharmaceutical and medicinal applications found for different compounds. The aim of this study was the evaluation of the antiproliferative activity of… read more here.
Keywords: c6h4 me2sn; me2sn cc5h4n; chemistry; c6h4 ... See more keywords
Reversible addition of tin(II) amides to nitriles.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt04060j
Abstract: Lappert's stannylene (Sn[N(SiMe3)2]2) has been reacted with various nitriles, dinitriles and trinitriles with the formation of heteroleptic amidotin(II) amidinates of the general formulae [RC(NSiMe3)2]SnN(SiMe3)2, R'{[C(NSiMe3)2]SnN(SiMe3)2}2 and R''{[C(NSiMe3)2]SnN(SiMe3)2}3, where R = Ph (1), 2-(CN)-C6H4 (2), 3-(CN)-C6H4… read more here.
Keywords: c6h4; c6h4 c6h4; nsime3 snn; sime3 ... See more keywords
Iron complexes of bridging azo ligands in aqueous solution: changes in the thermal switching mechanism on coordination and oxidation state of metal centres.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03790d
Abstract: Three azobenzenes CN(C6H4)-NN-(C5H4N) (py-iso), CN(C6H4)-NN-(C6H4)CN (cyano-iso) and CN(C6H4)-NN-(C6H4)NC (iso-iso) with good coordinating groups (pyridine, phenylcyano or phenylisocyano) at the ends of the diazenyl unit have been synthesized and fully characterised. These compounds have been used… read more here.
Keywords: c6h4; coordination; complexes bridging; mechanism ... See more keywords
Unmasking the constitution and bonding of the proposed lithium nickelate “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc01244h
Abstract: More than four decades ago, a complex identified as the planar homoleptic lithium nickelate “Li3NiPh3(solv)3” was reported by Taube and co-workers. This and subsequent reports involving this complex have lain dormant since; however, the absence… read more here.
Keywords: solv; c6h4; li3niph3 solv; c6h4 ligand ... See more keywords
Organometallic Complexes for Non-Linear Optics. 59. Syntheses and Optical Properties of Some Octupolar (N-Heterocyclic Carbene)gold Complexes
Sign Up to like & getrecommendations! Published in 2017 at "Australian Journal of Chemistry"
DOI: 10.1071/ch16321
Abstract: The syntheses of octupolar alkynes 1,3,5-{4-(4-HC≡CC6H4-1-C≡C)-3,5-Et2C6H2-1-C≡C}3C6H3 (4) and 1,3,5-{4-(4-HC≡CC6H4-1-C≡C-4-C6H4-1-C≡C)-3,5-Et2C6H2-1-C≡C}3C6H3 (6), diphenylamino-substituted 1,3,5-(4-Ph2NC6H4-1-C≡C)3C6H3 (7), 1,3,5-(4-Ph2NC6H4-1-C≡C-4-C6H4-1-C≡C)3C6H3 (8), 1,3,5-{4-(4-Ph2NC6H4-1-C≡C-4-C6H4-1-C≡C)-3,5-Et2C6H2-1-C≡C}3C6H3 (9), and 1,3,5-{4-(4-Ph2NC6H4-1-C≡C-4-C6H4-1-C≡C-4-C6H4-1-C≡C)-3,5-Et2C6H2-1-C≡C}3C6H3 (10), and (N-heterocyclic carbene)gold-appended 1,3,5-{[(NHC-iPr)Au]C≡C}3C6H3 (11), 1,3,5-{[(NHC-iPr)Au]C≡C-4-C6H4-1-C≡C}3C6H3 (12), 1,3,5-{4-([(NHC-iPr)Au]C≡C-4-C6H4-1-C≡C)-3,5-Et2C6H2-1-C≡C}3C6H3 (13), and 1,3,5-{4-([(NHC-iPr)Au]C≡C-4-C6H4-1-C≡C-4-C6H4-1-C≡C)-3,5-Et2C6H2-1-C≡C}3C6H3 (14) [NHC-iPr = κC-cyclo-CN(2,6-C6H3iPr2)CH=CHN(2,6-C6H3iPr2)] are reported.… read more here.
Keywords: et2c6h2 3c6h3; nhc ipr; c6h4 et2c6h2; c6h4 ... See more keywords