Articles with "c70" as a keyword



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A Bio‐Conjugated Fullerene as a Subcellular‐Targeted and Multifaceted Phototheranostic Agent

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Published in 2021 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202101527

Abstract: Fullerenes are candidates for theranostic applications because of their high photodynamic activity and intrinsic multimodal imaging contrast. However, fullerenes suffer from low solubility in aqueous media, poor biocompatibility, cell toxicity, and a tendency to aggregate.… read more here.

Keywords: bio conjugated; c70; subcellular targeted; conjugated fullerene ... See more keywords
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Identification of amphetamine as a stimulant drug by pristine and doped C70 fullerenes: a DFT/TDDFT investigation

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Published in 2021 at "Journal of Molecular Modeling"

DOI: 10.1007/s00894-021-04788-z

Abstract: The density functional theory (DFT) was used to examine the electronic reactivity and sensitivity of a pristine, Si, and Al-doped fullerene C70 with AM drug. AM drug has been shown to be physically absorbed by… read more here.

Keywords: adsorption; pristine doped; c70; drug ... See more keywords
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Selective and competitive adsorption behaviors of guest molecules in donor-acceptor conjugated macrocycles networks on liquid/solid interface

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Published in 2018 at "Applied Surface Science"

DOI: 10.1016/j.apsusc.2018.08.035

Abstract: Abstract The selective competitive adsorption of guest molecules C70 and coronene (COR) in the electron donor-acceptor conjugated macrocycles host systems were investigated by means of scanning tunneling microscope (STM). The assembled structures of macrocycle molecules… read more here.

Keywords: guest molecules; c70; competitive adsorption; donor acceptor ... See more keywords
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O6-Corona[6]arenes with Expanded Cavities for Specific Complexation with C70.

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Published in 2017 at "Organic letters"

DOI: 10.1021/acs.orglett.7b00409

Abstract: O6-Corona[3]arene[3]tetrazines with expanded cavities were synthesized by one-pot SNAr reaction between 3,6-dichlorotetrazine and aromatic diols. The macrocycle-to-macrocycle transformation involving IEDDA of tetrazine moieties with an enamine followed by denitrogenative aromatization afforded O6-corona[3]arene[3]pyridazines. O6-Corona[6]arenes adopted coronary… read more here.

Keywords: corona arene; c70; arenes expanded; corona arenes ... See more keywords
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M6L12 Nanospheres with Multiple C70 Binding Sites for 1O2 Formation in Organic and Aqueous Media

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Published in 2022 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.2c05507

Abstract: Singlet oxygen is a potent oxidant with major applications in organic synthesis and medicinal treatment. An efficient way to produce singlet oxygen is the photochemical generation by fullerenes which exhibit ideal thermal and photochemical stability.… read more here.

Keywords: organic aqueous; c70; m6l12 nanospheres; binding sites ... See more keywords
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Rational Functionalization of a C70 Buckybowl to Enable a C70:Buckybowl Co-crystal for Organic Semiconductor Applications.

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Published in 2020 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.9b12192

Abstract: Fullerene fragments, referred to as buckybowls, are garnering interest due to their distinctive molecular shapes and optoelectronic properties. Here we report the synthesis and characterization of a novel C70 subunit, diindeno[4,3,2,1-fghi:4',3',2',1'-opqr]perylene, that is substituted with… read more here.

Keywords: c70; c70 buckybowl; buckybowl enable; rational functionalization ... See more keywords
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Mesoporous fullerene C70 cubes with highly crystalline frameworks and unusually enhanced photoluminescence properties

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Published in 2018 at "Materials horizons"

DOI: 10.1039/c7mh00954b

Abstract: Here we report the synthesis of new mesoporous crystalline fullerene (C70) cubes (MCFCs) at a liquid–liquid interface between tert-butyl alcohol (TBA) and a solution of C70 in mesitylene under mild heat treatment. The highly crystalline… read more here.

Keywords: fullerene c70; c70; c70 cubes; photoluminescence properties ... See more keywords
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Direct conjugation with a zero length linker of fullerene C70 to ZnO quantum dots for multicolor light-emitting diodes

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Published in 2020 at "Materials horizons"

DOI: 10.1039/d0mh00449a

Abstract: Environmentally friendly metal oxide quantum dot (QD) nanostructures have become attractive alternative materials for replacing QDs containing toxic elements of Cd and Pb. Although many attempts have been proposed for optoelectronic applications of hybrid metal… read more here.

Keywords: fullerene c70; c70; zno; qds ... See more keywords
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Computational mining of endohedral C70 electrides: tri-metal alkali and alkaline-earth encapsulation.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt02919g

Abstract: C70 is the second most abundant fullerene next to C60. In this work, the exploration of C70 based electrides is proposed by theoretical encapsulation of group I/II trimetallic clusters into the C70 cage. Herein, we… read more here.

Keywords: c70; encapsulation; alkaline earth; computational mining ... See more keywords
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Broadband Visible Light-Absorbing [70]Fullerene-BODIPY-Triphenylamine Triad: Synthesis and Application as Heavy Atom-Free Organic Triplet Photosensitizer for Photooxidation

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Published in 2021 at "Molecules"

DOI: 10.3390/molecules26051243

Abstract: A broadband visible light-absorbing [70]fullerene-BODIPY-triphenylamine triad (C70-B-T) has been synthesized and applied as a heavy atom-free organic triplet photosensitizer for photooxidation. By attaching two triphenylmethyl amine units (TPAs) to the π-core of BODIPY via ethynyl… read more here.

Keywords: free organic; c70; heavy atom; organic triplet ... See more keywords
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Panchromatic Light-Absorbing [70]Fullerene-Perylene-BODIPY Triad with Cascade of Energy Transfer as an Efficient Singlet Oxygen Sensitizer

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Published in 2023 at "Molecules"

DOI: 10.3390/molecules28083534

Abstract: A panchromatic light-absorbing [70]fullerene-perylene-BODIPY triad (C70-P-B) was synthesized and applied as a heavy atom-free organic triplet photosensitizer for photooxidation. The photophysical processes were comprehensively investigated by the methods of steady-state spectroscopy, time-resolved spectroscopy, as well… read more here.

Keywords: c70; spectroscopy; perylene; singlet ... See more keywords