Titanium Imido Complexes via Displacement of -SiMe3 and C-H Bond Activation in a Ti(III) Amido Complex, Promoted by a Cyclic (Alkyl)(Amino) Carbene (cAAC).
Sign Up to like & getrecommendations! Published in 2017 at "European journal of inorganic chemistry"
DOI: 10.1002/ejic.201700295
Abstract: A strong σ-donating cyclic (alkyl)(amino) carbene (cAAC) triggers rearrangement of the silyl(aryl) amido ligand -N(SiMe3)Dipp (Dipp = 2,6-diisopropylphenyl) in the coordination sphere of titanium(III) to afford a novel zwitterionic titanium imido complex with a TiCH2SiMe2[cAAC]… read more here.
Keywords: imido; amino carbene; alkyl amino; titanium ... See more keywords
Control of metabolic predisposition to cardiovascular complications of chronic kidney disease by effervescent calcium magnesium citrate: a feasibility study
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Nephrology"
DOI: 10.1007/s40620-018-0559-2
Abstract: AimsCardiovascular (CV) complications are common in chronic kidney disease (CKD). Numerous metabolic disturbances including hyperphosphatemia, high circulating calciprotein particles (CPP), hyperparathyroidism, metabolic acidosis, and magnesium deficiency are associated with, and likely pathogenic for CV complications… read more here.
Keywords: citrate; study; caac; magnesium ... See more keywords
Mesomeric Acceleration Counters Slow Initiation of Ruthenium–CAAC Catalysts for Olefin Metathesis (CAAC = Cyclic (Alkyl)(Amino) Carbene)
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DOI: 10.1021/acscatal.2c03828
Abstract: Ruthenium catalysts bearing cyclic (alkyl)(amino)carbene (CAAC) ligands can attain very high productivities in olefin metathesis, owing to their resistance to unimolecular decomposition. Because the propagating methylidene species RuCl2(CAAC)(=CH2) is extremely susceptible to bimolecular decomposition, however,… read more here.
Keywords: alkyl amino; acceleration; caac; cyclic alkyl ... See more keywords
Carbene stabilized interconnected bis-germylene and its silicon analogue with small methyl substituents.
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DOI: 10.1039/c7dt01796k
Abstract: The cyclic alkyl(amino) carbene (cAAC) [:C{N-C6H3(2,6-IPr2)}(CMe2)2CH2] stabilized MeGeGeMe has been isolated in the molecular form with composition (cAAC)MeGe-GeMe(cAAC) (1) at room temperature. Compound 1 was synthesized from the reduction of MeGeCl3 using three equivalents of… read more here.
Keywords: bis germylene; stabilized interconnected; silicon; caac ... See more keywords
Isolation of base stabilized fluoroborylene and its radical cation.
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DOI: 10.1039/c9dt01899a
Abstract: Herein, we report the synthesis and characterization of the metal free low valent fluoroborylene [(Me-cAAC)2BF] (1) stabilized by cyclic (alkyl)(amino) carbene (cAAC). The fluoroborylene 1 is obtained by the reductive defluorination of Me-cAAC:BF3 with 2.0… read more here.
Keywords: cation; isolation base; stabilized fluoroborylene; radical cation ... See more keywords
Synthesis and structures of molecular beryllium Grignard analogues featuring terminal and bridging pseudohalides.
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DOI: 10.1039/d4dt02457e
Abstract: The carbene-stabilised beryllium Grignards [(CAAC)BeBrR] (R = CAACH 1a, Dur 1b; CAAC/H = 1-(2,6-diisopropylphenyl)-2,2,4,4-tetramethylpyrrolidin-2-yl/idene; Dur = 2,3,5,6-tetramethylphenyl) undergo salt metathesis with various pseudohalide salt precursors. Whereas with [NaNCS] the thiocyanato Grignards [(CAAC)Be(NCS)R] (R = CAACH… read more here.
Keywords: beryllium grignard; dur; beryllium; caac ... See more keywords
Streamlined synthetic assembly of α-chiral CAAC ligands and catalytic performance of their copper and ruthenium complexes
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DOI: 10.1039/d4sc04278f
Abstract: The unique electronic and steric parameters of chiral cyclic alkyl amino carbene (CAAC) ligands render them appealing steering ligands for enantioselective transition-metal catalyzed transformations. Due to the lack of efficient synthetic strategies to access particularly… read more here.
Keywords: copper ruthenium; caac ligands; caac; chiral caac ... See more keywords
OLED Microdisplay With Monolithically Integrated CAAC-OS FET and Si CMOS Achieved by Two-Dimensionally Arranged Silicon Display Drivers
Sign Up to like & getrecommendations! Published in 2024 at "IEEE Journal of the Electron Devices Society"
DOI: 10.1109/jeds.2024.3366938
Abstract: We developed an organic light-emitting diode (OLED)/oxide semiconductor (OS)/silicon (Si) display in which Si CMOS display drivers can be arranged two-dimensionally by monolithically stacking ${c}$ -axis-aligned crystalline oxide semiconductor (CAAC-OS) FETs over Si CMOS. A… read more here.
Keywords: silicon display; two dimensionally; caac; display ... See more keywords