113Cd as a Probe in NMR Studies of Allosteric Host‐Guest‐Ligand Complexes of Porphyrin Cage Compounds
Sign Up to like & getrecommendations! Published in 2022 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202200111
Abstract: Abstract Cadmium porphyrin cage compounds Cd1 and 113 Cd1 have been synthesized from the free base porphyrin cage derivative H21 and Cd(OAc)2 ⋅ 2 H2O or 113Cd(OAc)2 ⋅ 2 H2O, respectively. The compounds form allosteric complexes with the positively… read more here.
Keywords: porphyrin cage; cage; cage compounds; guest ... See more keywords
Electronic properties of RX2Al20 (R = La, Ce, Yb, Th, U; X = Ti, V, Cr and Mn) cage compounds
Sign Up to like & getrecommendations! Published in 2018 at "Computational Materials Science"
DOI: 10.1016/j.commatsci.2018.06.047
Abstract: Abstract Non-spin-polarized electronic structures and Fermi surface properties of RX 2 Al20 (R = La, Ce, Yb, Th, U; X = Ti, V, Cr, Mn) intermetallic compounds were calculated using the full potential all-electron local orbital (FPLO)… read more here.
Keywords: electronic properties; cage compounds; rx2al20 cage; properties rx2al20 ... See more keywords
Rapid and scalable synthesis of chiral porphyrin cage compounds
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.07.009
Abstract: Abstract An improved and scalable synthetic route to chiral porphyrin cage compounds, which will be used as catalytic machines for the encoding of information into polymers, has been developed. The porphyrin cage was made chiral… read more here.
Keywords: porphyrin cage; chiral porphyrin; cage compounds; cage ... See more keywords
Synthesis and Structure of Bismuth-Nitrogen Cage Compounds and Heterocubanes: [Cl-Bi(μ3-N-TMP)]4: A Dimer of a 1,3-Dichloro-cyclo-dibismadiazane.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b03221
Abstract: The reaction of TMP-NH2 [TMP = m,m-(CF3)2-C6H3] with 2 equiv of n-BuLi led to the in situ formation of Li2[N-TMP], which, after the addition of BiCl3, formed a [Cl-Bi(μ3-N-TMP)]4-type heterocubane in up to 30% yield.… read more here.
Keywords: tmp; structure bismuth; cage compounds; synthesis structure ... See more keywords
Theoretical studies on the propulsive and explosive performance of strained polycyclic cage compounds
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c6nj02444k
Abstract: Compounds consisting of a carbon-based cage have a highly strained molecular structure and have become the subject of interest in recent years because they possess high heat of formation and so are highly energetic. In… read more here.
Keywords: theoretical studies; studies propulsive; cage compounds; explosive performance ... See more keywords