Synthesis and Rearrangement of Cage [4.3.2]Propellanes that Contain a Spiro Linkage
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DOI: 10.1002/ejoc.201700617
Abstract: Rearranged cage ketones 6a and 6b are reported in eight linear synthetic steps starting with 2,5-dimethoxybenzaldehyde 9 without the involvement of protecting groups. In this regard, Diels‒Alder reaction, [2+2]photocycloaddition and Lewis acid promoted rearrangement with… read more here.
Keywords: contain spiro; cage propellanes; synthesis rearrangement; rearrangement cage ... See more keywords