Introduction of organogermyl functionalities to cage silsesquioxanes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt00557f
Abstract: In this work, we present the first example of highly efficient platinum-catalyzed hydrosilylation of vinyl- and allylgermanes with different types of silsesquioxanes and spherosilicates. This protocol allows the straightforward introduction of organogermyl functionalities with alkyl… read more here.
Keywords: functionalities cage; cage silsesquioxanes; introduction organogermyl; organogermyl functionalities ... See more keywords
Preparation of Tri(alkenyl)functional Open-Cage Silsesquioxanes as Specific Polymer Modifiers
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DOI: 10.3390/polym12051063
Abstract: The scientific reports on polyhedral oligomeric silsesquioxanes are mostly focused on the formation of completely condensed T8 cubic type structures and recently so-called double-decker derivatives. Herein, we report on efficient synthetic routes leading to trifunctionalized,… read more here.
Keywords: methodology; cage silsesquioxanes; tri alkenyl; open cage ... See more keywords