Caged Cyclopropenes with Improved Tetrazine Ligation Kinetics.
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DOI: 10.1021/acs.orglett.9b01177
Abstract: Activatable cyclopropenes are unreactive toward their inverse electron demand Diels-Alder reaction partner (e.g., s-tetrazines) until they are activated. The activation strategy is highly modular due to the cyclopropene's ability to be caged by various light-… read more here.
Keywords: caged cyclopropenes; tetrazine ligation; ligation; ligation kinetics ... See more keywords