Stoichiometric reactions and catalytic dehydrogenations of amine-boranes with calcium aryloxide.
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DOI: 10.1039/c9cc04698d
Abstract: Catalysis with the main-group metal calcium conventionally relies on σ-bond metathesis to initiate the reactions. Here, we report a calcium aryloxide based on the tridentate β-diketiminato ligand, which shows transition-metal-like reactivity with dialkylamine-boranes H3B·NHR2 (R… read more here.
Keywords: amine boranes; calcium aryloxide; stoichiometric reactions; catalytic dehydrogenations ... See more keywords