Synthesis, Structure and DFT Calculation of Bi- and Tridentate Ketiminate Ligands Assisted Aluminum Complexes: Potential Catalyst for Styrene Oxide-CO2 Cycloaddition Reaction
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DOI: 10.1039/d5nj03282b
Abstract: A series of ketiminate ligands, L1H-L4H are first synthesized by coupling of benzoylacetone with phenylhydrazine, 2-methoxy-5-methylaniline, (+/-)-tetrahydrofurfurylamine, N-(2-aminoethyl)-piperidine, respectively, in adequate yields. Deprotonation of L1H-L4H with one equivalent of AlMe3... read more here.
Keywords: structure dft; calculation tridentate; synthesis structure; dft calculation ... See more keywords