Structure, magnetic properties and DFT calculations of azido-copper(II) complexes with different azido-bonding, nuclearity and dimensionality
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DOI: 10.1039/c7nj04150k
Abstract: Four bridged-azido Cu(II) complexes were synthesized and structurally characterized: [Cu2(Et3en)2(μ1,1-N3)2(N3)2] (1), [Cu2(ip2en)2(μ1,1-N3)2(N3)2] (2), catena-[Cu2(Et2Meen)2(μ1,3-N3)3]ClO4 (3) and catena-[Cu(ambza)(μ1,1,3-N3)2] (4), where Et3en = N,N,N′-triethyl-1,2-diaminoethane; ip2en = N,N′-diisopropyl-1,2-diaminoethane; Et2Meen = N,N-diethyl-N′-methyl-1,2-diaminoethane; and ambza = 2-aminobenzylamine. Single crystal X-ray… read more here.
Keywords: calculations azido; magnetic properties; structure; dft calculations ... See more keywords