Temperature‐Enhanced Supramolecular Polymer Adhesion Provided by Concurrent Utilization of Calix[4]Pyrrole and Crown Ether Molecular Recognition
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202503854
Abstract: Low molecular weight (LMW) supramolecular polymer adhesives built up from functional small molecules suffer from temperature sensitivity, which limits their utility in applications requiring high temperature ranges. It is reported here a linear supramolecular polymer… read more here.
Keywords: temperature; adhesion; pyrrole crown; polymer ... See more keywords
Immobilizing surface halide in perovskite solar cells via calix[4]pyrrole.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced materials"
DOI: 10.1002/adma.202301871
Abstract: The halide diffusion across the charge-transporting layer followed by reaction with metal electrode represents a critical factor limiting the long-term stability of perovskite solar cells (PSCs). In this work, we report a supramolecular strategy with… read more here.
Keywords: calix pyrrole; surface halide; solar cells; surface ... See more keywords
Binding of Linear Anions and Formation of Anion Encapsulated Dimeric Capsular Assembly by Cis‐5,15‐bis(3,5‐trifluorometylphenyl)calix[4]pyrrole
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.202400217
Abstract: Cis‐5,15‐bis(3,5‐trifluorometylphenyl)calix[4]pyrrole (1) forms stable 1/1 complexes with linear anions such as N3‐, SCN‑ and NCO‑ with the highest affinity for NCO‐ anion in acetonitrile solution. Crystallization of receptor 1 with TBASCN and (TMA)2SO4 resulted in… read more here.
Keywords: trifluorometylphenyl calix; linear anions; bis trifluorometylphenyl; calix pyrrole ... See more keywords
Basketing nanopalladium into calix[4]pyrrole as an efficient catalyst for Mizoroki-Heck reaction
Sign Up to like & getrecommendations! Published in 2017 at "Arabian Journal of Chemistry"
DOI: 10.1016/j.arabjc.2016.06.019
Abstract: Abstract An approach to synthesize calix[4]pyrrole protected palladium nanoparticles (PdNPs) employed for catalytic Mizoroki-Heck C-C coupling reaction is reported. The nanoparticles are synthesized in water using novel calix[4]pyrrole tetrahydrazide (CPTH) as a reducing as well… read more here.
Keywords: heck; calix pyrrole; reaction; mizoroki heck ... See more keywords
Recognition, Sensing, and Trapping of Bicarbonate Anions with a Dicationic meso-Bis(benzimidazolium) Calix[4]pyrrole
Sign Up to like & getrecommendations! Published in 2017 at "Chem"
DOI: 10.1016/j.chempr.2017.10.007
Abstract: Summary A meso -aryl calix[4]pyrrole derivative bearing benzimidazolium groups at the two diametrical meso positions was synthesized. The receptor acts as an effective host for the bicarbonate anion at concentrations as low as 4 nM. A… read more here.
Keywords: anion; meso; calix pyrrole; benzimidazolium ... See more keywords
Novel calix[4]pyrrole assembly: Punctilious recognition of F - and Cu +2 ions
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.08.006
Abstract: Abstract A new tetra hydroxyl methoxy substituted calix[4]pyrrole (HMCP) has been synthesized and found to form stable complex with F − ions and Cu +2 ions. The red-shift in absorption band of HMCP was observed… read more here.
Keywords: pyrrole; assembly punctilious; calix pyrrole; novel calix ... See more keywords
Aryl-Extended and Super Aryl-Extended Calix[4]pyrroles: Design, Synthesis, and Applications.
Sign Up to like & getrecommendations! Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00839
Abstract: ConspectusProteins exhibit high-binding affinity and selectivity, as well as remarkable catalytic performance. Their binding pockets are hydrophobic but also contain polar and charged groups to contribute to the binding of polar organic molecules in aqueous… read more here.
Keywords: calix pyrrole; calix pyrroles; extended calix; calix ... See more keywords
Thallium(I) Salts: New Partners for Calix[4]pyrroles.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c00555
Abstract: Calix[4]pyrrole 1 can form host-guest complexes with certain thallium salts, for example, TlF, not only in the gas phase but also in solution and in the solid state. The complexation of TlF by calix[4]pyrrole 1… read more here.
Keywords: microscopy; partners calix; calix pyrrole; salts new ... See more keywords
Calix[3]pyrrole: A Missing Link in Porphyrin-Related Chemistry.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c06331
Abstract: A long-standing question in porphyrin chemistry is why pyrrole monomers selectively form tetrapyrrolic macrocycles, whereas the corresponding tripyrrolic macrocycles are never observed. Calix[3]pyrrole, a tripyrrolic porphyrinogen-like macrocycle bearing three sp3-carbon linkages, is a missing link… read more here.
Keywords: calix pyrrole; missing link; chemistry;
Calix[4]pyrrole-Based Azo-Bridged Porous Organic Polymer for Bromine Capture.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c08327
Abstract: The toxicity, corrosiveness, and volatility of elemental bromine presents challenges for its safe storage and transportation. Purification from other halogens is also difficult. Here, we report an easy-to-prepare calix[4]pyrrole-based azo-bridged porous organic polymer (C4P-POP) that… read more here.
Keywords: calix pyrrole; azo bridged; bromine; capture ... See more keywords
Probing Ion-Receptor Interactions in Halide Complexes of Octamethyl Calix[4]Pyrrole.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c13445
Abstract: Ion receptors are molecular hosts that bind ionic guests, often with great selectivity. The interplay of solvation and ion binding in anion host-guest complexes in solution governs the binding efficiency and selectivity of such ion… read more here.
Keywords: ion receptor; octamethyl calix; ion; receptor interactions ... See more keywords