Aryl-Extended and Super Aryl-Extended Calix[4]pyrroles: Design, Synthesis, and Applications.
Sign Up to like & getrecommendations! Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00839
Abstract: ConspectusProteins exhibit high-binding affinity and selectivity, as well as remarkable catalytic performance. Their binding pockets are hydrophobic but also contain polar and charged groups to contribute to the binding of polar organic molecules in aqueous… read more here.
Keywords: calix pyrrole; calix pyrroles; extended calix; calix ... See more keywords
Unexpected halide anion binding modes in meso-bis-ethynyl picket-calix[4]pyrroles: effects of meso-π (ethynyl) extension.
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DOI: 10.1039/c8cc04393k
Abstract: meso-Ethynyl extended aryl-picket calix[4]pyrroles 2 and 3 are designed and synthesized by directly anchoring arylethynyl groups at diametrically opposed meso-positions. The critical roles of direct ethynyl linkers are manifested through the isolation of unexpected host-anion… read more here.
Keywords: meso ethynyl; picket calix; calix; calix pyrroles ... See more keywords
Synthetic access to calix[3]pyrroles via meso-expansion: hosts with diverse guest chemistry.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc01447h
Abstract: Calix[3]pyrroles were synthesized for the first time. These macrocycles display versatile guest binding ability based on the bridges connecting the two α-positions of the tripyrrane moiety e.g. with an ethene bridge they showed colorimetric sensing… read more here.
Keywords: calix pyrroles; synthetic access; chemistry; pyrroles via ... See more keywords