Polymerization of N-Substituted Glycine N-Thiocarboxyanhydride through Regioselective Initiation of Cysteamine: A Direct Way toward Thiol-Capped Polypeptoids
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DOI: 10.1021/acs.macromol.8b00259
Abstract: Because of the high reactivity, N-carboxyanhydride (NCA) can be initiated by the thiol group. On the contrary, N-thiocarboxyanhydride (NTA) is more stable and is able to tolerate it. Herein, we apply cysteamine as a regioselective… read more here.
Keywords: thiol; glycine thiocarboxyanhydride; polymerization; capped polypeptoids ... See more keywords