Melt Electrospinning Writing of Poly‐Hydroxymethylglycolide‐co‐&egr;‐Caprolactone‐Based Scaffolds for Cardiac Tissue Engineering
Sign Up to like & getrecommendations! Published in 2017 at "Advanced Healthcare Materials"
DOI: 10.1002/adhm.201700311
Abstract: Current limitations in cardiac tissue engineering revolve around the inability to fully recapitulate the structural organization and mechanical environment of native cardiac tissue. This study aims at developing organized ultrafine fiber scaffolds with improved biocompatibility… read more here.
Keywords: melt electrospinning; cardiac tissue; caprolactone; tissue ... See more keywords
Selective One‐Step Aerobic Oxidation of Cyclohexane to ϵ‐Caprolactone Mediated by N‐Hydroxyphthalimide (NHPI)
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201900282
Abstract: The selective one‐step aerobic oxidation of cyclohexane to ϵ‐caprolactone was achieved in the presence of N‐hydroxyphthalimide (NHPI) and aldehyde under mild conditions. Remarkably, 12 % of cyclohexane was converted with a selectivity of 77 % of ϵ‐caprolactone… read more here.
Keywords: selective one; oxidation; caprolactone; step aerobic ... See more keywords
Biocatalytic Production of a Nylon 6 Precursor from Caprolactone in Continuous Flow
Sign Up to like & getrecommendations! Published in 2022 at "Chemsuschem"
DOI: 10.1002/cssc.202200811
Abstract: Abstract 6‐Aminocaproic acid (6ACA) is a key building block and an attractive precursor of caprolactam, which is used to synthesize nylon 6, one of the most common polymers manufactured nowadays. (Bio)‐production of platform chemicals from renewable… read more here.
Keywords: caprolactone; acid; continuous flow; biocatalytic production ... See more keywords
Biocatalytic production of Ɛ-caprolactone using Geotrichum candidum cells immobilized on functionalized silica.
Sign Up to like & getrecommendations! Published in 2020 at "Applied microbiology and biotechnology"
DOI: 10.1007/s00253-020-10875-7
Abstract: Immobilization of the Geotrichum candidum (CCT 1205) cell with functionalized silica creates promising biocatalysts for production of ɛ-caprolactone. The results obtained by immobilization of the whole cell on SiO2-NH2 and SiO2-SH supports indicate that the… read more here.
Keywords: geotrichum candidum; production caprolactone; functionalized silica; caprolactone ... See more keywords
Synthesis and self-assembly behavior of POSS tethered amphiphilic polymer based on poly(caprolactone) (PCL) grafted with poly(acrylic acid) (PAA) via ROP, ATRP, and CuAAC reaction
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Polymer Research"
DOI: 10.1007/s10965-016-1171-6
Abstract: This investigation reports the preparation and self-assembly behavior of polyhedral oligomeric silsesquioxane (POSS) containing poly(caprolactone)-graft-poly(acrylic acid) (POSS-PCL-graft-PAA) polymer. This article focuses on the self-assembly behavior of POSS tethered amphiphilic graft copolymer. In this investigation, POSS… read more here.
Keywords: poss; graft; polymer; caprolactone ... See more keywords
Enhancing the grafting amount of Poly(ε-caprolactone) on MgO nanoparticles by modifying with ethylene glycol for improving mechanical properties of Poly(ε-caprolactone)
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Polymer Research"
DOI: 10.1007/s10965-017-1374-5
Abstract: A new surface modification method to improve the graft polymerization of ε-caprolactone (CL) on MgO surface was developed. The MgO nanoparticles were first modified with ethylene glycol (EG), and then used for initiating graft polymerization… read more here.
Keywords: mgo; caprolactone mgo; mgo nanoparticles; caprolactone ... See more keywords
Palladium nanoparticles supported onto stereocomplexed poly(lactic acid)-poly(ε-caprolactone) copolymers for selective partial hydrogenation of phenylacetylene
Sign Up to like & getrecommendations! Published in 2017 at "Rendiconti Lincei"
DOI: 10.1007/s12210-017-0600-8
Abstract: AbstractPalladium nanoparticles, generated by hydrogen reduction of Pd acetate, coordinated to a stereocomplexed 2,2′-bipyridine end-functionalized poly(lactic acid)-poly(ε-caprolactone) copolymer showed enhanced catalytic activity and chemoselectivity for the partial reduction of phenylacetylene compared to the reference system… read more here.
Keywords: poly lactic; acid poly; caprolactone; poly caprolactone ... See more keywords
Sustainable production of chemical intermediates for nylon manufacture: A techno-economic analysis for renewable production of caprolactone
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Engineering Research and Design"
DOI: 10.1016/j.cherd.2018.05.026
Abstract: Abstract Caprolactone is a precursor for the synthesis of caprolactam, the key monomer for nylon-6 which is produced globally at a scale of 4 million tonnes per annum. This work describes and assesses a bio-based… read more here.
Keywords: production; analysis; techno economic; caprolactone ... See more keywords
Synthesis and antibacterial behavior of bio-composite materials-based on poly(ε-caprolactone)/bentonite
Sign Up to like & getrecommendations! Published in 2021 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2021.110602
Abstract: Abstract Several clay minerals as inorganic fillers were incorporated to aliphatic polyester by various procedures. The target of enhancing the physicochemical properties of the resulting composite material leading thereby to overcome the limitations of neat… read more here.
Keywords: synthesis antibacterial; caprolactone bentonite; based poly; caprolactone ... See more keywords
Ring-opening polymerization of ε-caprolactone with recyclable and reusable squaric acid organocatalyst
Sign Up to like & getrecommendations! Published in 2021 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2021.110643
Abstract: Abstract With the increasing requirements concerning healthy and environmental issues of modern-day society, green chemistry and atomic economy have become the consensus of researchers and manufacturers, enabling us to explore much facile way to prepare… read more here.
Keywords: ring opening; squaric acid; opening polymerization; caprolactone ... See more keywords
Synthesis and characterization of two new biobased poly(pentylene 2,5-furandicarboxylate-co-caprolactone) and poly(hexamethylene 2,5-furandicarboxylate-co-caprolactone) copolyesters with enhanced enzymatic hydrolysis properties
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Degradation and Stability"
DOI: 10.1016/j.polymdegradstab.2019.01.004
Abstract: Abstract Herein, two fully renewable copolyester series, namely poly(pentylene 2,5-furandicarboxylate-co-caprolactone) (PPeCFs) and poly(hexamethylene 2,5-furandicarboxylate-co-caprolactone) (PHeCFs) were successfully synthesized with combining e-caprolactone (CL) with poly(pentylene 2,5-furandicarboxylate) (PPeF) and poly(hexamethylene 2,5-furan dicarboxylate) (PHeF) with different molar ratios.… read more here.
Keywords: pentylene furandicarboxylate; poly pentylene; furandicarboxylate caprolactone; caprolactone ... See more keywords