Further evidence in favour of a carbanion mechanism for glycolate oxidase
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DOI: 10.1002/2211-5463.13534
Abstract: The flavoenzyme glycolate oxidase oxidizes glycolic acid to glyoxylate and the latter, more slowly, to oxalate. It is a member of an FMN‐dependent enzyme family that oxidizes l‐2‐hydroxy acids to keto acids. There has been… read more here.
Keywords: glycolate oxidase; oxidase; evidence; carbanion ... See more keywords
Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations
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DOI: 10.1021/acs.accounts.0c00620
Abstract: Conspectus The use of photocatalysis in organic chemistry has encountered a surge of novel transformations since the start of the 21st century. The majority of these transformations are driven by the generation and subsequent reaction… read more here.
Keywords: photocatalytic generation; strategies photocatalytic; carbanion; generation ... See more keywords
Capturing Reactive Carbanions by Microdroplets.
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DOI: 10.1021/jacs.2c01577
Abstract: Carbanions appear in many organic or biological reactions as fleeting intermediates, prohibiting direct observation or spectroscopic measurement. An aqueous environment is known to rapidly annihilate a carbanion species, reducing its lifetime to as short as… read more here.
Keywords: capturing reactive; reaction; microdroplets capturing; reactive carbanions ... See more keywords