Bicyclic (alkyl)(amino)carbene (BICAAC) in a dual role: activation of primary amides and CO2 towards catalytic N-methylation
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DOI: 10.1039/d3sc01216f
Abstract: Herein, we report the first catalytic methylation of primary amides using CO2 as a C1 source. A bicyclic (alkyl)(amino)carbene (BICAAC) exhibits dual role by activating both primary amide and CO2 to carry out this catalytic… read more here.
Keywords: alkyl amino; amino carbene; carbene bicaac; primary amides ... See more keywords