A luminescent lipid mimetic iridium(III) N-heterocyclic carbene complex for membrane labelling.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2020.111047
Abstract: Labelling phospholipid membranes with luminophores without altering the biophysical characteristics of the system is particularly challenging due to the small size of the phospholipid molecules and the sensitivity of membrane properties to the presence of… read more here.
Keywords: luminescent lipid; carbene complex; iii heterocyclic; lipid mimetic ... See more keywords
Synthesis, X-ray structure, DFT calculations and anticancer activity of a selenourea coordinated gold(I)-carbene complex
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.08.003
Abstract: Abstract A gold(I)-carbene complex, [Au(IPr)(Seu)]PF6 (1), where Seu = Selenourea and IPr = 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene, was prepared using [Au(IPr)Cl] and characterized by elemental analysis, IR, and NMR (1H, 13C, 77Se) methods. The crystal structure of 1 was determined by single-crystal… read more here.
Keywords: seu; carbene complex; gold carbene; ipr ... See more keywords
Cooperative Bond Activation Reactions with Ruthenium Carbene Complex PhSO2(Ph2PNSiMe3)C═Ru(p-cymene): Ru═C and N–Si Bond Reactivity
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.7b00254
Abstract: The synthesis of ruthenium carbene complex PhSO2(Ph2PNSiMe3)C═Ru(p-cymene) (3) and its application in cooperative bond activation reactions were studied. Compound 3 is accessible via salt metathesis using the dilithium methandiide ligand or alternatively via dehydrohalogenation of… read more here.
Keywords: bond; ruthenium carbene; carbene complex; complex phso2 ... See more keywords
Diastereoselective Direct Catalytic Asymmetric Mannich-Type Reactions of Alkylnitriles with a Ni(II)-Carbene Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01624
Abstract: Despite recent advances in reactions using alkylnitriles as carbon nucleophiles, diastereoselective direct catalytic asymmetric reactions, in which two consecutive chiral centers could be controlled, remain largely unexplored. Herein, we report the addition of alkylnitriles (such… read more here.
Keywords: direct catalytic; diastereoselective direct; type; carbene complex ... See more keywords
A dicopper(i)-dimesoionic carbene complex as a click catalyst: mechanistic implications.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt01882d
Abstract: A dicopper(i) complex comprising a dimesoionic carbene and an acetate-bridge is synthesized and fully characterized. This complex is a potent pre-catalyst for the azide-alkyne cycloaddition reaction. A full kinetic investigation shows a first order in… read more here.
Keywords: dimesoionic carbene; dicopper dimesoionic; carbene complex; complex click ... See more keywords
Pd-N-heterocyclic carbene complex catalysed C–H bond activation of 2-isobutylthiazole at the C5 position with aryl bromides
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj00514f
Abstract: An effective and efficient catalytic system has been reported for the synthesis of C5-arylated 2-isobutylthiazoles. read more here.
Keywords: catalysed bond; activation isobutylthiazole; bond activation; heterocyclic carbene ... See more keywords
A mesoionic carbene complex of manganese in five oxidation states.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00097k
Abstract: Reaction between a carbazole-based mesoionic carbene ligand and manganese(II) iodide results in the formation of a rare air-stable manganese(IV) complex after aerobic workup. Cyclic voltammetry reveals the complex to be stable in five oxidation states.… read more here.
Keywords: five oxidation; mesoionic carbene; carbene complex; oxidation states ... See more keywords
Construction of polymeric Cu(I) N-heterocyclic carbene complex utilizing terpyridine-Fe(II) as linkers: formation of an efficient and recyclable catalyst
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1430788
Abstract: Abstract A metal-coordination-driven self-assembly using the predesigned building block has been developed. Herein, the catalytic active NHC–Cu(I) units were introduced into the terpyridine metal coordination polymers. The self-assembled architecture, as a heterogeneous catalyst, was successfully… read more here.
Keywords: complex utilizing; carbene complex; construction polymeric; polymeric heterocyclic ... See more keywords