Dinuclear silver(I)-N-heterocyclic carbene complexes: Synthesis, characterization and larvicidal activity of bis-imidazolium dinuclear silver(I)-N-heterocyclic carbene complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.07.030
Abstract: New synthesized bis-imidazolium salts that are linked by xylyl derivatives moiety, 1-4 was reacted with Ag2O to facilitate the formation of dinuclear Ag(I)-N-heterocyclic carbene (NHC) complexes, 5-8, respectively. All the synthesized ligand salts and complexes… read more here.
Keywords: carbene complexes; dinuclear silver; silver heterocyclic; imidazolium ... See more keywords
Synthesis and structural investigation of mono- and dimetallic N-heterocyclic carbene complexes of group VII transition metals
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.02.031
Abstract: Abstract N-heterocyclic carbene complexes of group VII transition metals (Mn and Re) were synthesized and the electronic and structural aspects theoretically investigated. The synthesis yielded carbene complexes of type [M x (CO) y L(NHC)] where… read more here.
Keywords: carbene complexes; vii transition; group vii; carbene ... See more keywords
Fluorinated N-Heterocyclic carbene complexes. Applications in catalysis
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121364
Abstract: Abstract N-heterocyclic carbenes (NHC) are one of the most versatile type of ligands described up to date, this being in part due to the facile modulation of their electronic and steric properties. Hence, they can… read more here.
Keywords: carbene complexes; chemistry; applications catalysis; complexes applications ... See more keywords
Extreme g-Tensor Anisotropy and Its Insensitivity to Structural Distortions in a Family of Linear Two-Coordinate Ni(I) Bis-N-heterocyclic Carbene Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02413
Abstract: We report a new series of homoleptic Ni(I) bis-N-heterocyclic carbene complexes with a range of torsion angles between the two ligands from 68° to 90°. Electron paramagnetic resonance measurements revealed a strongly anisotropic g-tensor in… read more here.
Keywords: carbene complexes; extreme tensor; bis heterocyclic; heterocyclic carbene ... See more keywords
Bonding Nature of "Ionic Carbenes" in [M3(μ3-CH2)]-Containing Compounds: The Covalent Interaction.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01726
Abstract: While a series of trinuclear rare-earth metal methylene (divalent >CH2) complexes with the so-called "ionic carbene" have been known for decades, the nature of metal-carbene interactions in this class of compounds remains elusive. Herein, a… read more here.
Keywords: carbene complexes; carbene; bonding nature; covalent interaction ... See more keywords
Finding Design Principles of OLED Emitters through Theoretical Investigations of Zn(II) Carbene Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03301
Abstract: In this work, Zn(II) carbene complexes carrying a dianionic 1,2-dithiolbenzene (dtb) or 1,2-diolbenzene (dob) ligand were investigated regarding their suitability as organic light-emitting diode (OLED) emitter. For the optimization of the complexes, density functional-based methods… read more here.
Keywords: carbene complexes; finding design; design principles; principles oled ... See more keywords
N-Heterocyclic Carbene Complexes of Nickel(II) from Caffeine and Theophylline: Sustainable Alternative to Imidazol-2-ylidenes.
Sign Up to like & getrecommendations! Published in 2022 at "Organometallics"
DOI: 10.1021/acs.organomet.2c00019
Abstract: Xanthines, such as caffeine and theophylline, are abundant natural products that are often present in foods. Leveraging renewable and benign resources for ligand design in organometallic chemistry and catalysis is one of the major missions… read more here.
Keywords: carbene complexes; caffeine theophylline; chemistry; imidazol ylidenes ... See more keywords
Accessing Heteroannular Benzoxazole and Benzimidazole Scaffolds via Carbodiimides Using Azide–Isocyanide Cross-Coupling as Catalyzed by Mesoionic Singlet Palladium Carbene Complexes Derived from a Phenothiazine Moiety
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.2c07875
Abstract: The coupling of aryl and aliphatic azides with isocyanides yielding carbodiimides (8–17) were efficiently catalyzed by well-defined structurally characterized trans-(MIC)PdI2(L) [MIC = 1-CH2Ph-3-Me-4-(CH2N(C6H4)2S)-1,2,3-triazol-5-ylidene, L = NC5H5 (4), MesNC (5)], trans-(MIC)2PdI2 (6), and cis-(MIC)Pd(PPh3)I2 (7) type… read more here.
Keywords: carbene complexes; singlet palladium; azide isocyanide; mesoionic singlet ... See more keywords
Carbene Complexes of Neptunium
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02152
Abstract: Since the advent of organotransuranium chemistry six decades ago, structurally verified complexes remain restricted to π-bonded carbocycle and σ-bonded hydrocarbyl derivatives. Thus, transuranium-carbon multiple or dative bonds are yet to be reported. Here, utilizing diphosphoniomethanide… read more here.
Keywords: carbene complexes; transuranium; complexes neptunium; chemistry ... See more keywords
Mechanochemical synthesis of Cu(i)-N-heterocyclic carbene complexes
Sign Up to like & getrecommendations! Published in 2020 at "Green Chemistry"
DOI: 10.1039/d0gc01923b
Abstract: We report a general, operationally simple and scalable mechanochemical method for the synthesis of [Cu(Cl)(NHC)] complexes. This solid-state and solvent-less methodology was shown to be applicable to a wide range of NHC ligand precursors, allowing… read more here.
Keywords: carbene complexes; chemistry; mechanochemical synthesis; synthesis heterocyclic ... See more keywords
Carbocyclic pincer carbene complexes of ruthenium: syntheses and reversible hydrogenation.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt02266k
Abstract: The ruthenium carbene pincer complex 2 was synthesized treating the benzo annulated cycloheptatriene bisphosphine 1 with RuCl3. Addition of three equivalents of hydrogen to the carbocyclic carbene complex 2 was achieved in reaction of 2… read more here.
Keywords: ruthenium; carbocyclic pincer; carbene complexes; pincer carbene ... See more keywords