Single-Electron Oxidation of Carbene-Coordinated Pnictinidenes-Entry into Heteroleptic Radical Cations and Metalloid Clusters.
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DOI: 10.1021/acs.inorgchem.2c00249
Abstract: Stable heavy main group element radicals are challenging synthetic targets. Although several strategies have been developed to stabilize such odd-electron species, the number of heavier pnictogen-centered radicals is limited. We report on a series of… read more here.
Keywords: electron; carbene coordinated; radical cations; electron oxidation ... See more keywords
N-Heterocyclic Carbene-Coordinated M(II) (M = Yb, Sm, Ca) Bisamides: Expanding the Limits of Intermolecular Alkene Hydrophosphination.
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DOI: 10.1021/acs.inorgchem.2c00698
Abstract: A series of NHC-stabilized amido compounds (NHC)nM[N(SiMe3)2]2 (M = Yb(II), Sm(II), Ca(II); n = 1, 2) showed remarkable catalytic efficiency in addition of PhPH2 and PH3 to alkenes under mild conditions and low catalyst loading.… read more here.
Keywords: addition; carbene coordinated; hydrophosphination; coordinated bisamides ... See more keywords