Tridentate complexes of group 4 bearing bis-aryloxide N-heterocyclic carbene ligand: Structure, spin density and charge states
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2021.138888
Abstract: Abstract Metal carbene complexes represent an ubiquitous class of compounds in organomettalic chemistry able to trigger a wealth of catalytic reactions of both fundamental and industrial processes. By resorting to first principles approaches, we focus… read more here.
Keywords: carbene ligand; spin; structure; charge ... See more keywords
Pd-catalyzed enantioselective cyclopropanation of nitriles with mono substituted allyl carbonates enabled by the bulky N-heterocyclic carbene ligand.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc01960j
Abstract: A highly efficient catalyst for Pd-catalyzed cyclopropanation was developed using a bulkier N-heterocyclic carbene ligand, with which the nitriles reacted with mono substituted allyl reagents to afford cyclopropanes in high yields with high cyclopropanation/allylation and… read more here.
Keywords: cyclopropanation; mono substituted; carbene ligand; substituted allyl ... See more keywords