A Green Synthesis of Carbene‐Metal‐Amides (CMAs) and Carboline‐Derived CMAs with Potent in vitro and ex vivo Anticancer Activity
Sign Up to like & getrecommendations! Published in 2022 at "ChemMedChem"
DOI: 10.1002/cmdc.202200135
Abstract: The modularity and ease of synthesis of carbene‐metal‐amide (CMA) complexes based on the coinage metals (Au, Ag, Cu) and N‐heterocyclic carbenes (NHCs) as ancillary ligands pave the way for the expansion of their applications beyond… read more here.
Keywords: synthesis carbene; vitro vivo; carbene metal; synthesis ... See more keywords
Excited-State Lifetime Modulation by Twisted and Tilted Molecular Design in Carbene-Metal-Amide Photoemitters
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DOI: 10.1021/acs.chemmater.2c01938
Abstract: Carbene–metal–amides (CMAs) are an emerging class of photoemitters based on a linear donor–linker–acceptor arrangement. They exhibit high flexibility about the carbene–metal and metal–amide bonds, leading to a conformational freedom which has a strong influence on… read more here.
Keywords: state; carbene metal; excited state; metal ... See more keywords
Thermally Activated Delayed Fluorescence Mechanism of a Bicyclic "Carbene-Metal-Amide" Copper Compound: DFT/MRCI Studies and Roles of Excited-State Structure Relaxation.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03603
Abstract: Herein we investigated the luminescence mechanism of one "carbene-metal-amide" copper compound with thermally activated delayed fluorescence (TADF) using density functional theory (DFT)/multireference configuration interaction, DFT, and time-dependent DFT methods with the polarizable continuum model. The… read more here.
Keywords: state; carbene metal; dft; mechanism ... See more keywords
Improved synthetic routes to N-heterocyclic carbene-metal-diketonato complexes of gold and copper.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02276a
Abstract: In our search for simple synthetic routes to N-heterocyclic carbene (NHC)-metal complexes and their derivatives, we herein report an operationally simple, expedient and scalable method to obtain the widely used NHC-metal-diketonates. The reported complexes are… read more here.
Keywords: copper; carbene metal; improved synthetic; routes heterocyclic ... See more keywords
Tailoring Carbene–Metal–Amides for Thermally Activated Delayed Fluorescence: A Computationally Guided Study on the Effect of Cyclic (Alkyl)(amino)carbenes
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28114398
Abstract: Gold-centered carbene–metal–amides (CMAs) containing cyclic (alkyl)(amino)carbenes (CAACs) are promising emitters for thermally activated delayed fluorescence (TADF). Aiming at the design and optimization of new TADF emitters, we report a density functional theory study of over… read more here.
Keywords: alkyl amino; carbene metal; thermally activated; cyclic alkyl ... See more keywords