Atropisomeric N‐Heterocyclic Carbene‐Palladium(II) Complexes: Influence of the Backbone Substitution
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202300780
Abstract: In order to facilitate the synthesis of NHC precursors as well as to incorporate new moieties, the influence of the NHC backbone substitution was investigated within the concept of atropisomeric NHC‐metal complexes. A series of… read more here.
Keywords: backbone substitution; heterocyclic carbene; influence; atropisomeric heterocyclic ... See more keywords
Synthesis of ferrocene indanone derivatives via trinuclear N-heterocyclic carbene palladium(II)-catalyzed cyclocarbonylation of o-bromoarylferrocene
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.01.016
Abstract: Abstract A new route to ferrocene indanone derivatives has been developed via the trinuclear N-heterocyclic carbene palladium(II)-catalyzed carbonylative C-C bond formation. Under a CO atmosphere, using o-bromoarylferrocene as substrate, this reaction proceeded smoothly to give… read more here.
Keywords: via trinuclear; trinuclear heterocyclic; carbene palladium; ferrocene indanone ... See more keywords
C2-Symmetric Atropisomeric N-Heterocyclic Carbene-Palladium(II) Complexes: Synthesis, Chiral Resolution and Application in enantioselective α-Arylation of Amides
Sign Up to like & getrecommendations! Published in 2023 at "Dalton Transactions"
DOI: 10.1039/d3dt01182h
Abstract: The concept of atropisomeric N-heterocyclic carbene (NHC)-metal complexes was extended to NHCs possessing a C2-symmetry and implemented to prepare of palladium-based complexes. An in-depth study of the NHC precursors and... read more here.
Keywords: carbene palladium; atropisomeric heterocyclic; symmetric atropisomeric; heterocyclic carbene ... See more keywords