Metalloradical intermediates in electrocatalytic reduction of CO2 to CO: Mn versus Re bis-N-heterocyclic carbene pincers.
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DOI: 10.1039/c9dt04691g
Abstract: This work examines the relative reactivities of ReI and MnI tricarbonyl pyridine-2,6-bis-N-heterocyclic carbene pincers M(CO)3CNCBnX (M = Re, Mn and X = Cl and Br) towards catalysis for the electrochemical conversion of CO2 to CO.… read more here.
Keywords: reduction; bis heterocyclic; carbene pincers; co2 ... See more keywords