Mechanistic Investigation of Biocatalytic Heme Carbenoid Si−H Insertions
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DOI: 10.1002/cctc.201801755
Abstract: Recent studies reported the development of biocatalytic heme carbenoid Si−H insertions for the selective formation of carbon‐silicon bonds, but many mechanistic questions remain unaddressed. To this end, a DFT mechanistic investigation was performed which reveals… read more here.
Keywords: heme; biocatalytic heme; carbenoid insertions; heme carbenoid ... See more keywords