Catalytic Intermolecular Carboamination of Unactivated Alkenes via Directed Aminopalladation.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b06520
Abstract: An intermolecular 1,2-carboamination of unactivated alkenes proceeding via a Pd(II)/Pd(IV) catalytic cycle has been developed. To realize this transformation, a cleavable bidentate directing group is used to control the regioselectivity of aminopalladation and stabilize the… read more here.
Keywords: carboamination unactivated; aminopalladation; intermolecular carboamination; reaction ... See more keywords
Intermolecular Carboamination of Unactivated Alkenes.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07023
Abstract: Herein, we report the first example of group transfer radical addition of O-vinylhydroxylamine derivatives onto unactivated alkenes. By utilizing O-vinylhydroxylamine derivatives as both the N- and C-donors, this reaction enables intermolecular carboamination of unactivated alkenes… read more here.
Keywords: carboamination; carboamination unactivated; intermolecular carboamination; unactivated alkenes ... See more keywords