Lewis Superacidic Heavy Pnictaalkene Cations: Comparative Assessment of Carbodicarbene-Stibenium and Carbodicarbene-Bismuthenium Ions.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03135
Abstract: We report a comprehensive assessment of Lewis acidity for a series of carbone-stibenium and -bismuthenium ions using the Gutmann-Beckett (GB) method. These new antimony and bismuth cations have been synthesized by halide abstractions from (CDC)PnBr3… read more here.
Keywords: stibenium; bismuthenium ions; cdc; carbodicarbene ... See more keywords
Synthesis and Characterization of Bis(phosphine)carbodicarbene Complexes of Iron, Cobalt, and Nickel
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DOI: 10.1021/acs.organomet.1c00241
Abstract: The synthesis and characterization of nickel, cobalt, and iron complexes of the bis(phosphine)carbodicarbene (CDC) ligand 1 is described. The square-planar complexes can be synthesized without the isolation of the deprotonated carbodicarbene ligand, and three different synthetic methods… read more here.
Keywords: cobalt; phosphine carbodicarbene; bis phosphine; synthesis ... See more keywords
Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c11861
Abstract: Borenium ions, originally synthesized as fundamentally important laboratory curiosities, have attracted significant attention due to their applications in catalysis and frustrated Lewis pair chemistry. However, investigations of the materials properties of these types of compounds… read more here.
Keywords: borafluorenium; stable thermoluminescent; air stable; carbodicarbene ... See more keywords