Flexibility of the Carbodiphosphorane, (Ph3P)2C: Structural Characterization of a Linear Form.
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DOI: 10.1021/acs.inorgchem.7b00381
Abstract: X-ray diffraction studies demonstrate that crystals of the carbodiphosphorane, (Ph3P)2C, obtained from solutions in benzene, exhibit a linear P-C-P interaction. This observation is in contrast to the highly bent structures that have been previously reported… read more here.
Keywords: carbodiphosphorane ph3p; linear form; characterization linear; structural characterization ... See more keywords