Copper(I)-Catalyzed Synthesis of Unsymmetrical All-Carbon Bis-Quaternary Centers at the Opposing α-Carbons of Cyclohexanones
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DOI: 10.1021/acs.orglett.2c01890
Abstract: We describe a new synthetic reaction that generates all-carbon bis-quaternary centers at the opposing side of α-carbons in cyclohexanone with four different substituents in a controlled manner. Catalyzed by Cu(MeCN)4BF4 salt, this chemistry is proposed… read more here.
Keywords: carbon bis; centers opposing; bis quaternary; copper catalyzed ... See more keywords