Long Carbon-Carbon Bonding beyond 2 Å in Tris(9-fluorenylidene)methane.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c07431
Abstract: We report on our investigation of C-C bonding longer than 2.0 Å, which can be realized by perpendicularly facing two fluorenyl rings in the title compound. A small orbital overlap between the distantly positioned carbon… read more here.
Keywords: long carbon; beyond tris; carbon; carbon bonding ... See more keywords
Conformational control of N-methyl-N,N'-diacylhydrazines by noncovalent carbon bonding in solution.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc00943a
Abstract: In recent years, some X-ray structural and computational evidence has emerged for noncovalent carbon bonding (C-bond). However, evidence of C-bonds in solution is limited. Herein, from the conformational analyses of strategically designed N-methyl-N,N'-diacylhydrazines, we for… read more here.
Keywords: noncovalent carbon; carbon bonding; methyl diacylhydrazines; conformational control ... See more keywords