Carbon-carbon bonds with CO2: Insights from computational studies
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.02.020
Abstract: Abstract In this mini-review, we provide an overview of recent computational studies on homogeneous transition metal-catalyzed carbon-carbon bond formation with CO2. We cover substitution and addition reactions involving different metals (mainly Ni, Rh, Cu) and… read more here.
Keywords: carbon bonds; bonds co2; carbon; bond formation ... See more keywords
Deoxygenation of Ethers To Form Carbon-Carbon Bonds via Nickel Catalysis.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b02326
Abstract: In this article a successful protocol was developed to construct carbon-carbon bonds by the extrusion of the O atom of ethers via nickel catalysis in the presence of reductants. This methodology is featured as a… read more here.
Keywords: carbon bonds; nickel catalysis; carbon; carbon carbon ... See more keywords
Trivalent metal ions promote the malic enzyme-catalyzed building of carbon–carbon bonds from CO2and pyruvate
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DOI: 10.1039/d0nj03449e
Abstract: Malic enzyme (ME) from chicken liver (EC 1.1.1.40) is an enzyme that catalyzes the decarboxylation of malate into pyruvate and CO2 and the reverse reaction that introduces CO2 as a carboxy-group to pyruvate to form… read more here.
Keywords: carbon bonds; pyruvate co2; carbon; pyruvate ... See more keywords
Quantum dots visibly forge carbon bonds.
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DOI: 10.1126/science.356.6338.595-e
Abstract: Organic Chemistry Chemists are late to the game that plants play of using visible light to make carbon-carbon bonds. Nonetheless, they have made up for lost time over the past decade, applying light activation of… read more here.
Keywords: carbon bonds; carbon; visibly forge; dots visibly ... See more keywords
Formation of Carbon-Carbon Bonds Mediated by Hypervalent Iodine Reagents Under Metal-free Conditions
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DOI: 10.2174/1385272824666200211093103
Abstract: During the past several decades, hypervalent iodine reagents have been widely used in various organic transformations. Specifically, these exclusive classes of reagents have been extensively used for the construction of carbon-carbon bonds. This review aims… read more here.
Keywords: carbon bonds; hypervalent iodine; carbon; chemistry ... See more keywords