Intrinsic infrared absorption for carbon–fluorine bonding in fluorinated nanodiamond
Sign Up to like & getrecommendations! Published in 2020 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2020.01.028
Abstract: IR spectroscopy of fluorinated detonation nanodiamond demonstrates that an intense absorption band at ∼1344 cm–1 and two smaller ones at ∼1324 and ∼1258 cm–1 form the extended low wave-number wing of the observed consolidated spectrum… read more here.
Keywords: absorption; carbon fluorine; intrinsic infrared; infrared absorption ... See more keywords
Enantioselective construction of remote tertiary carbon–fluorine bonds
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DOI: 10.1038/s41557-019-0289-7
Abstract: The carbon–fluorine bond engenders distinctive physicochemical properties and significant changes to general reactivity. The development of catalytic, enantioselective methods to set stereocentres that contain a benzylic C–F bond is a rapidly evolving goal in synthetic… read more here.
Keywords: construction; bond; carbon fluorine; chemistry ... See more keywords
Breaking Carbon–Fluorine Bonds with Main Group Nucleophiles
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DOI: 10.1055/s-0039-1690738
Abstract: In this Account we describe a series of new reactions that we, and others, have reported that involve the transformation of C–F bonds into C–Mg, C–Al, C–Si, C–Fe and C–Zn bonds. We focus on the… read more here.
Keywords: group; main group; group nucleophiles; reactions nucleophiles ... See more keywords
Carbon-11 and Fluorine-18 Labeled Amino Acid Tracers for Positron Emission Tomography Imaging of Tumors
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DOI: 10.3389/fchem.2017.00124
Abstract: Tumor cells have an increased nutritional demand for amino acids (AAs) to satisfy their rapid proliferation. Positron-emitting nuclide labeled AAs are interesting probes and are of great importance for imaging tumors using positron emission tomography… read more here.
Keywords: amino; fluorine labeled; imaging tumors; positron emission ... See more keywords