Stereoelectronic Modulation of a Single-Molecule Junction through a Tunable Metal-Carbon dπ-pπ Hyperconjugation.
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DOI: 10.1021/jacs.3c02733
Abstract: Conjugated molecules play a critical role in the construction of single-molecule devices. However, most conventional conjugated molecules, such as hydrocarbons, involve only a pπ-pπ conjugation of light elements. While the metal d-orbitals can introduce abundant… read more here.
Keywords: metal carbon; single molecule; metal; carbon hyperconjugation ... See more keywords